Yb^(3＋),Er^(3＋)共掺BaGd_2ZnO_5材料的制备及其上转换发光效率  

Preparation and Up-conversion Efficiencies of Yb^(3+),Er^(3+) Co-doped BaGd_2ZnO_5

作　　者：杨艳民[1] 焦福运[1] 苏红新[1] 李自强[1] 焦金鹏[2] 刘云峰[3] 李志强[1] 

机构地区：[1]河北大学物理科学与技术学院,河北保定071002 [2]航天长征火箭技术有限公司,北京100176 [3]河北大学工商学院.河北保定071002

出　　处：《发光学报》2012年第12期1319-1323,共5页Chinese Journal of Luminescence

基　　金：国家自然科学基金(50902042);河北省自然科学基金(E2010000283);中国博士后科研基金(20100480840)资助项目

摘　　要：采用溶胶-凝胶法制备了含有不同Yb3+,Er3+掺杂浓度的BaGd2ZnO5上转换发光材料,测量了这些样品在不同激发光密度下的上转换光发射功率及上转换效率。实验结果表明:在不同激发光密度下,所有样品的光发射功率都存在极大值,其中Yb3+掺杂摩尔分数为4%,Er3+掺杂摩尔分数为1%时样品的最大发射光功率可达20 mW;样品的上转换绝对效率也存在极大值,随着Yb3+和Er3+浓度增加,绝对效率的极大值向较低激发光密度方向移动,在Yb3+掺杂摩尔分数为9%,Er3+掺杂摩尔分数为3%时样品的上转换效率达到最高,绝对效率为3.2%,极值效率最大值为6.9%。BaGd2ZnO5 phosphors with different doping concentrations of Yb3＋,Er3＋ were prepared by using the sol-gel method.Up-conversion fluorescence powers and efficiencies were measured under different excitation density.The obtained data show that each sample has a maximum value in emission power.Among those sample,the sample of doping Yb3＋（4%）,Er3＋（1%） has the highest power of 20 mW.Each sample had a maximum value of up-conversion absolute fluorescence efficiency.This value shifts to the lower exciting density with the increasing content of Yb3＋ and Er3＋.The highest efficiency is 3.2% for Yb3＋（9%） and Er3＋（3%） sample,and the highest fluorescence efficiency is 6.9%.

关 键 词：BaGd2ZnO5 上转换 氧化物 Yb3+ Er3+ 

分 类 号：O482.31[理学—固体物理]