循环流化床灰对聚羧酸减水剂竞争吸附的影响研究  

Study on the Mechanism of Competitive Adsorption of Circulating Fluidized Bed Ash and Cement to Poly Carboxylic Acid Water Reducing Agent

作　　者：陈敏[1] 宋少民[1] 高霞[2] 

机构地区：[1]北京建筑工程学院北京市绿色建筑与节能技术重点实验室,北京100044 [2]北京科技大学土木与交通工程学院,北京100083

出　　处：《北京建筑工程学院学报》2012年第4期19-23,共5页Journal of Beijing Institute of Civil Engineering and Architecture

摘　　要：为研究循环流化床灰对聚羧酸减水剂竞争吸附的影响,通过在Ⅱ级粉煤灰中掺加无水硫酸纳、二水硫酸钙和氧化铁的方式来改变粉煤灰中三氧化硫和氧化铁含量,使其化学成分接近循环流化床灰,利用成分单因素分析的方法,测试减水剂水泥浆体的净浆流动度、zeta电位和混凝土性能.研究结果表明循环流化床灰中的三氧化硫和氧化铁对聚羧酸减水剂的吸附有明显负面影响,当可溶性硫酸盐掺量达到胶凝材料的3%、氧化铁掺量达到6%时,相应浆体均失去流动性.Zeta电位试验表明随着无水硫酸钠和氧化铁掺量的增大,Zeta电位绝对值越小,粒子间相互斥力越弱,分散性越差,分散体系就越不稳定.混凝土性能试验表明无水硫酸钠和氧化铁的掺入使得混凝土的流动性和抗压强度均变小,坍落度由220 mm降至125 mm,强度降低幅度最高达45%.In order to study on the effect of competitive adsorption of circulating fluidized bed ash and cement to poly carboxylic acid water reducing agent, by adding anhydrous sodium sulfate, dihydrate calcium sulphate and iron oxide into grade 11 fly ash to change the content of sulfur trioxide and iron oxide, its chemical composition close to circulating fluidized bed ash＇s is made, and the fuidity of cement past, zeta potential adding and concrete performance are tested. The results show that the dissolved sulfate and iron oxide in circulating fluidized bed ash have negative impact on adsorption of poly carboxylic acid water reducing agent. When the dosage of dissolved sulfate and iron oxide respectively reach 3% ,6% of the total cementing material,the corresponding paste both lost fluidity. Zeta potential tests indicate that the absolute of zeta potential gets smaller as the increase of dosage of dissolved sulfate and iron oxide, meanwhile repulsion between particles gets weaker, and dispersion becomes worse and dispersion system was more unstable. Concrete performance experiments show that the fluidity and compressive strength of concrete become smaller as sodium sulfate and iron oxide are incorporated in grade II fly ash, stump decreased from 220 mm to 125 mm, the highest strength reduce reached to 45%.

关 键 词：循环流化床灰 聚羧酸减水剂 硫酸盐 氧化铁 竞争吸附 

分 类 号：TU528[建筑科学—建筑技术科学]