双酚S型EP的制备及其复合体系粘接性能的研究  

Study on preparation of bisphenol S-epoxy resin and bonding properties of composite system

作　　者：田振宇[1,2] 林欣[2,3] 张军营[2,3] 程珏[2,3] 

机构地区：[1]常州大学,江苏常州213164 [2]北京化工大学常州先进材料研究院,江苏常州213164 [3]北京化工大学碳纤维及功能高分子教育部重点实验室,北京100029

出　　处：《中国胶粘剂》2012年第12期1-3,14,共4页China Adhesives

基　　金：江苏省科技支撑项目"耐高温双酚S环氧树脂制备及固化性能的研究"(BE2010066);常州市微电子化学材料研发公共技术平台基金项目(CZ2010003)

摘　　要：以双酚S单体、ECH(环氧氯丙烷)为原料,在碱性条件下制得双酚S型EP(环氧树脂);然后以双酚S型EP/双酚A型EP作为复合EP,采用柔性固化剂制得复合EP胶粘剂。研究结果表明:当固化剂为D230时,复合EP胶粘剂的剪切强度相对最大;以复合EP胶粘剂胶接不同基材,则相应胶接件的剪切强度随双酚S型EP或D230含量增加均呈先升后降态势,并且在w(D230)=40%、w(双酚S型EP)=30%(相对于总树脂质量而言)时相对最大。With bisphenol S monomer, ECH （epichlorohydrin） as raw materials, a bisphenol S-EP （epoxy resin） was prepared under alkaline condition. Then,with bisphenol S-EP/bisPhenol A-EP as composite paonomers,a composite EP adhesive was prepared by soft curing agent. The research results showed that the composite EP adhesive had the relatively maximal shear strength when D230 was used as curing agent. The shear strength of corresponding cementing sample had trends of rise-fall with increasing bisphenol S-EP or D230 contents when the composite EP adhesive was used for bonding different substrates, and its shear strength was relatively maximal when mass fractions of D230 and bisphenol S-EP were 40% and 30% in total resins respectively.

关 键 词：双酚S型环氧树脂 柔性固化剂 环氧树脂 胶粘剂 剪切强度 

分 类 号：TQ433.437[化学工程] TQ314.256