Separation of Salbutamol by Nano-baskets of Calix[4]arene Bearing Sulfonyl-carboxamides in Partial-cone Conformation  

作　　者：MOKHTARI Bahram POURABDOLLAH Kobra 

机构地区：[1]Razi Chemistry Research Center(RCRC),Shahreza Branch,Islamic Azad University

出　　处：《Chemical Research in Chinese Universities》2012年第6期1112-1118,共7页高等学校化学研究（英文版）

基　　金：Supported by the Project of Islamic Azad University(Shahreza Branch);the Iran Nanotechnology Initiative Council

摘　　要：Salbutamol,which increases the muscle mass and decreases the adipose tissue,is misused as nutrient repartitioning agent in the livestock.The novelty of this work is the determination of salbutamol in the livestock meat via new bonded-phases bearing eight derivatives of p-tert-calix[4]arene in partial-cone conformation.The new synthesized bonded-phases were characterized and optimized.The bonding interactions of solute and stationary-phases were examined and the main interactions were reported.The salbutamol levels in six samples of livestock meat were analyzed and the results reveal that for the best bonded-phases,the limit of detection（LOD） and limit of quantitation（LOQ） were 0.02 and 0.06 μg/mL,respectively.Salbutamol,which increases the muscle mass and decreases the adipose tissue,is misused as nutrient repartitioning agent in the livestock.The novelty of this work is the determination of salbutamol in the livestock meat via new bonded-phases bearing eight derivatives of p-tert-calix[4]arene in partial-cone conformation.The new synthesized bonded-phases were characterized and optimized.The bonding interactions of solute and stationary-phases were examined and the main interactions were reported.The salbutamol levels in six samples of livestock meat were analyzed and the results reveal that for the best bonded-phases,the limit of detection（LOD） and limit of quantitation（LOQ） were 0.02 and 0.06 μg/mL,respectively.

关 键 词：NANO-BASKET Bonded-phase Partial-cone conformation CALIX[4]ARENE SALBUTAMOL 

分 类 号：O641.6[理学—物理化学]