金属次卟啉二甲酯催化氧化苯乙烯制苯甲醛  

Preparation of Benzaldehyde Through Oxidation of Styrene Catalyzed by Metallo-deuteroporphyrin Dimethyl Esters

作　　者：赵东辉[1] 胡炳成[1] 孙呈郭[1] 邓全知[1] 

机构地区：[1]南京理工大学化工学院南京210094

出　　处：《应用化学》2013年第1期22-27,共6页Chinese Journal of Applied Chemistry

基　　金：江苏省自然科学基金(BK2009386);江苏省研究生创新基金(CXZZ11_0263)资助项目

摘　　要：将金属次卟啉二甲酯用作叔丁基过氧化氢(TBHP)氧化苯乙烯制苯甲醛的催化剂。考察了催化剂、氧化剂用量、反应温度、时间、溶剂和不同金属次卟啉二甲酯[M(DPDME)]对苯乙烯转化率及苯甲醛选择性的影响,初步探索了反应机理。结果表明,金属次卟啉二甲酯能够顺利地选择性催化氧化苯乙烯生成苯甲醛。以0.002 mmol锰次卟啉二甲酯[ClMn(DPDME)]为催化剂,0.4 mmol TBHP为氧化剂,1 mmol苯乙烯为底物,5 mL CH3CN/H2O(体积比4∶1)为溶剂,反应温度75℃,常压反应20 h,苯乙烯的转化率达到98.3%,苯甲醛的选择性为92.7%。In the presence of ten-butyl hydroperoxide （TBHP）, metallo-deuteroporphyrin dimethyl esters [ M（DPDME） ] were used as catalysts in the oxidation of styrene. We have investigated the effects of the amount of the catalyst, the amount of the oxidant, reaction temperature, time, solvents and metallo- deuteroporphyrin dimethyl esters with different central metals on the conversion of styrene and the selectivity of benzaldehyde. The mechanism of the reaction was also discussed. The results indicated that the M （DPDME） could efficiently catalyze selective oxidation of styrene to benzaldehyde in good yields. Under the conditions of 0. 002 mmol C1Mn （DPDME） as the catalyst, 0. 4 mmol TBHP as the oxidatant, 1 mmol styrene as the substrate, CH3CN（4 mL）/H20（ 1 mL） as the solvent, reaction temperature of 75℃, atmospheric pressure, and a reaction time of 20 h, the conversion of styrene reached 98.3% with the benzaldehyde selectivity of 92. 7%.

关 键 词：金属次卟啉二甲酯 苯乙烯 催化氧化 

分 类 号：O621[理学—有机化学]