纤维素基表面活性剂的研究进展及在造纸工业中的应用  

Research Progress on Cellulose-based Surfactants and the Application in Papermaking Industry

作　　者：贝俊杰[1] 曹云峰[1] 

机构地区：[1]南京林业大学 江苏省制浆造纸科学与技术重点实验室,江苏南京210037

出　　处：《纤维素科学与技术》2012年第4期65-72,共8页Journal of Cellulose Science and Technology

基　　金："江苏省青蓝工程中青年学术带头人培养对象"省教育厅资助课题(164105308);江苏高校优势学科建设工程资助项目

摘　　要：纤维素基表面活性剂具有可生物降解、无污染等特性,具有广泛的应用前景。表面活性剂具有双亲结构,纤维素基表面活性剂通过各种化学改性的方法在纤维素骨架上引入亲水端和疏水端,使整个分子具有表面活性。文章综述了离子型和非离子型纤维素基表面活性剂的合成,以纤维素或其衍生物为原料,通过取代、聚合等方法引入长链烷基等作为疏水基团,离子结构或聚醚结构作为亲水基团,合成的表面活性剂表现出良好的表面性能,并具有高分子表面活性剂的特性。纤维素基表面活性剂在造纸工业中的助留剂和涂料分散剂方面有一定的应用,并有望用于白水处理和废纸脱墨工段。而进一步降低产品的成本并开发更高效、功能更多样的纤维素基表面活性剂将成为未来的研究方向。The application prospects of cellulose-based surfactants are brightening for its characteristics such as biodegradability and pollution-free. The surfactant possesses amphiphilic structures. The hydrophilic side and hydrophobic side are induced on cellulose skeleton by chemical modifications to prepare the cellulose-based surfactants. A brief review is given regarding the synthesis of ionic and non-ionic cellulose-based surfactants. The long-chain alkyl group and ionic structure or polyester structures are induced into cellulose and its derivatives as hydrophobic and hydrophilic groups by substitution or polymerization. The synthetic surfactants have favorable properties such as surface activities and polymer properties. It can be used as retention aid and pigment dispersants in papermaking industry and is willing to be applied in white water treatment end and waste paper deinking end. To further reduce the cost of the product and develop more efficient and versatile cellulose-based surfactants will be the direction of future research.

关 键 词：纤维素 表面活性剂 离子型 非离子型 

分 类 号：TQ352.79[化学工程] TQ423.9