Hybrid molecular nanostructures with donor-acceptor chains  

作　　者：YANG Liu GUAN CuiZhong YUE Wan WU JingYi YAN HuiJuan ZHANG Xu WANG ZhaoHui ZHAN XiaoWei LI YuLiang WANG Dong WAN LiJun 

机构地区：[1]Institute of Chemistry,Chinese Academy of Sciences (CAS) [2]Graduate University of CAS

出　　处：《Science China Chemistry》2013年第1期124-130,共7页中国科学（化学英文版）

基　　金：supports from National Basic Research Program of China (2011CB808700 and 2011CB932300);National Natural Science Foundation of China (21121063,91023013)

摘　　要：We have fabricated hybrid molecular chain structures formed by electron acceptor compound 1 and electron donor molecules 2 and 3 at the liquid/solid interface of graphite surface.The structural details of the mono-component and the binary assemblies are revealed by high resolution scanning tunneling microscopy (STM).Compound 1 can form two well-ordered lamellar patterns at different concentrations.In the co-adsorption structures,compounds 2 and 3 can insert into the space between molecular chains of compound 1 and form large area well-ordered nanoscale phase separated lamellar structures.The unit cell parameters for the coassemblies can be "flexibly" adjusted to make the electron donors and acceptors perfectly match along the molecular chains.Scanning tunneling spectroscopy (STS) results indicate that the electronic properties of individual molecular donors and acceptors are preserved in the binary self-assembly.These results provide molecular insight into the nanoscale phase separation of organic electron acceptors and donors on surfaces and are helpful for the fabrication of surface supramolecular structures and molecular devices.We have fabricated hybrid molecular chain structures formed by electron acceptor compound 1 and electron donor molecules 2 and 3 at the liquid/solid interface of graphite surface.The structural details of the mono-component and the binary assemblies are revealed by high resolution scanning tunneling microscopy （STM）.Compound 1 can form two well-ordered lamellar patterns at different concentrations.In the co-adsorption structures,compounds 2 and 3 can insert into the space between molecular chains of compound 1 and form large area well-ordered nanoscale phase separated lamellar structures.The unit cell parameters for the coassemblies can be ＂flexibly＂ adjusted to make the electron donors and acceptors perfectly match along the molecular chains.Scanning tunneling spectroscopy （STS） results indicate that the electronic properties of individual molecular donors and acceptors are preserved in the binary self-assembly.These results provide molecular insight into the nanoscale phase separation of organic electron acceptors and donors on surfaces and are helpful for the fabrication of surface supramolecular structures and molecular devices.

关 键 词：phase separation donor and acceptor self-assembly hybrid molecular nanostructure liquid/solid interface 

分 类 号：TB383.1[一般工业技术—材料科学与工程]