金属-有机纳米管  

Metal-Organic Nanotubes

作　　者：戴昉纳 柳云骐 崔敏 王宗廷 冯锡兰 

机构地区：[1]中国石油大学(华东)理学院重质油国家重点实验室,青岛266580

出　　处：《化学进展》2013年第1期69-76,共8页Progress in Chemistry

基　　金：山东省优秀中青年科学家奖励基金项目(No.BS2012CL038);第51批博士后科学基金面上一等资助(No.2012M510106);中国石油大学(华东)自主创新科研计划(No.12CX04092A)资助

摘　　要：金属-有机纳米管(metal-organic nanotubes,MONTs)是由无机金属离子和有机配体通过自组装方法构筑的具有纳米级隧道的框架结构,由于其管状结构独特的内部孔径、多样的拓扑结构及其在诸多领域的多重应用,越来越受到关注,是无机化学和配位化学等领域研究中的一个热点。本文评述了金属-有机纳米管的存在形式和构建策略,包括杯芳烃及环糊精类配体构筑MONTs、常规吡啶氮类配体或芳香羧酸配体构筑MONTs和混合配体策略构筑MONTs,着重介绍了近年来国内外金属-有机纳米管研究领域的最新成果和进展,并指出了金属-有机纳米管领域今后的研究方向。By self-assembly methods, metal-organic nanotubes constructed from metal ions and bridging organic ligands have afforded a promising approach toward the synthesis of open nanoporous materials. In recent years, the design and synthesis of nanotubular frameworks have attracted intensive attention due to their uniform, fixed internal diameters, impressive topological structures and versatile applications in many areas. This paper give a comprehensive review of the metal-organic nanotubes categories, including the metal-organic nanotubes constructed from calixarene and cyclodextrin ligands, ordinary ligands and mixed ligands, highlights the latest achievements and progress in field of metal-organic nanotubes. The future research directions of the metal-organic nanotubes is pointed out at last.

关 键 词：金属-有机配合物 纳米管 构筑策略 

分 类 号：O641.4[理学—物理化学] TB383[理学—化学]