烷基酚阴离子表面活性剂的合成与应用进展  

Synthesis and application progress of alkylphenol-based anionic surfactants

作　　者：孙守双 何志强 方云 

机构地区：[1]食品胶体与生物技术教育部重点实验室江南大学化学与材料工程学院,江苏无锡214122

出　　处：《化学研究与应用》2013年第1期13-19,共7页Chemical Research and Application

基　　金："十一五"国家科技支撑计划项目(2007BAE52B01)资助;江苏省精细石油化工重点实验室开放基金项目(KF0903)资助;江南大学博士研究生科学研究基金项目(JUDCF09007)资助

摘　　要：将本实验室最新研究成果与相关文献报导相结合,介绍了目前以烷基酚为原料合成阴-非离子表面活性剂、Extended表面活性剂和Gemini表面活性剂的最新动态,特别注重它们在三次采油等非直接环境排放型应用场合的高效合理利用。指出深入开发区域选择性硫酸化/磺化、硫酸酯盐转磺酸盐、羟基直接氧化合成羧酸盐以及烷基酚偶联合成Gemini骨架等技术对于合理和高效利用烷基酚具有重要意义。The synthesis progress of alkylphenol-based anionic-nonionic surfactants, Extended surfactants and Gemini surfactants was introduced in this paper based on the recent experimental results of our laboratory and the other relative reports. The attention was especially focused on applying the above suffactants in some cases involving indirectly environmental discharges such as tertiary oil recovery. In order to utilize alkylphenols high efficiently it was significant to develop techniques of regioselectively sulfating/sul- fonating,converting sulfonates from sulfates, preparing carboxylates by direct oxidation of hydroxyl and synthesizing skeletons of Gemini surfactants by coupling of alkylphenols.

关 键 词：烷基酚 阴离子表面活性剂 Extended表面活性剂 GEMINI表面活性剂 合成 应用 

分 类 号：TQ423[化学工程]