三光气与酚制备三氯甲氧基甲酸芳酯研究  

Research on reaction of triphosgene and phenols for preparing aryl trichloromethylcarbonate

作　　者：余卫国[1] 陈维[1] 史海波[1] 柳达春[1] 

机构地区：[1]浙江医药高等专科学校,浙江宁波315100

出　　处：《化学研究与应用》2013年第1期65-68,共4页Chemical Research and Application

基　　金：浙江省教育厅项目(Y201018453)资助;浙江省2009年应用化学重中之重开放基金项目(56310101638)资助

摘　　要：研究了不同取代酚与三光气的反应,得到七种未见报道的新化合物,以IR、MS、1H NMR、13C NMR对产物进行了表征,并探索得到合适的反应催化剂、反应物浓度配比、反应时间,讨论了酚上不同取代基对反应的影响,收率在78.5～90.5%之间。The synthesis of aryl triehloromethylearbonates from phenols and triphosgene were studied, seven new compounds were synthesized,the products were characterized by IR, MS, 1H NMR and 13 c NMR. Suitable catalyst, reaction time and reactant ratio were explored and determined, influence on the different substituted group in the phenols were also discussed. The reaction yields were from 78.5% to 90. 5%.

关 键 词：三光气 取代酚 亲核试剂 三氯甲氧基甲酸芳酯 

分 类 号：O625.53[理学—有机化学]