叶蜡石对PET/ABS/磷酸蜜铵盐(MP)复合材料性能的影响初探  

Influences of Pyrophyllite on the Properties of PET/ABS/MP Blends

作　　者：郑成[1,2,3] 肖荔人[1,2,3] 钱庆荣[2,3,4] 刘欣萍[2,3,4] 黄宝铨[2,3,4] 许兢[2,3,4] 陈庆华[2,3,4] 

机构地区：[1]福建师范大学材料科学与工程学院,福建福州350117 [2]福建省环境友好高分子材料工程技术研究中心,福建福州350117 [3]福建省改性塑料开发基地,福建福州350117 [4]福建师范大学环境科学与工程学院,福建福州350117

出　　处：《福建师范大学学报（自然科学版）》2013年第1期75-80,共6页Journal of Fujian Normal University：Natural Science Edition

基　　金：福建省自然科学基金资助项目(2011J01287)

摘　　要：采用叶蜡石协效提高聚对苯二甲酸乙二醇酯(PET)/丙烯腈-苯乙烯-丁二烯共聚物(ABS)/磷酸蜜胺盐(MP)复合材料体系的阻燃性能,通过力学性能测试、极限氧指数测试、垂直燃烧实验、热重分析、熔体流动速率测试、扫描电镜分析以及动态频率扫描测试,研究叶蜡石对PET/ABS/MP复合材料性能的影响.实验结果表明,加入适量的叶蜡石可在一定程度上提高复合体系的拉伸强度、弯曲强度、缺口冲击强度和熔体流动速率;当叶蜡石质量分数为4%时,其与MP协效阻燃性能最好,残炭率最高;体系的储能模量(G')与损耗模量(G″)随叶蜡石增加呈现先下降后上升的趋势.Pyrophyllite was employed to enhance the synergistic flame retardancy for PET/ ABS/MP blends. The influences of different proportions of pyrophyllite on various properties of PET/ABS/MP blends were studied by mechanical test, melt flow rate test, LOI, UL-94, TG, SEM and dynamic frequency sweep test. The results show that the tensile strength, flexural strength, notched impact strength and melt flow rate of PET/ABS/MP blends increase with increas- ing pyrophyllite to an appropriate amount. 4% pyrophyllite is found to be the optimum concentration for enhancement of the synergistic flame retardancy and charring of PET/ABS/MP blends. It is also clear that raising the dosage of pyrophyllite results in increasing the storage modulus （G＇） and the loss modulus （G＂） of the system to a peak value and decreasing subsequently.

关 键 词：聚对苯二甲酸乙二醇酯 丙烯腈-苯乙烯-丁二烯共聚物 磷酸蜜胺盐 叶蜡石 阻燃性能 

分 类 号：TQ334[化学工程—橡胶工业]