临安冬夏季SO_2、NO_2和O_3体积分数特征及与气象条件的关系  

Characteristics of SO_2, NO_2, O_3 volume fractions and their relationship with weather conditions at Linan in summer and winter

作　　者：范洋[1,2] 樊曙先[2] 张红亮[1] 祖繁[1] 孟庆紫[1] 何佳宝[1] 

机构地区：[1]南京信息工程大学大气物理学院,江苏南京210044 [2]南京信息工程大学中国气象局大气物理与大气环境重点开放实验室,江苏南京210044

出　　处：《大气科学学报》2013年第1期121-128,共8页Transactions of Atmospheric Sciences

基　　金：国家自然科学基金资助项目(41275151);江苏省青蓝工程"云雾降水物理学与气溶胶研究"创新团队项目;江苏高校优势学科建设工程资助项目(PAPD)

摘　　要：对临安大气本底站2003—2004年冬、夏季二氧化氮(NO2)、二氧化硫(SO2)、臭氧(O3)进行了分析。结果表明:冬季NO2和SO2平均体积分数分别为19.48×10-9和35.74×10-9,而夏季的平均体积分数分别为4.81×10-9和8.12×10-9,冬季高于夏季;O3在夏季的平均体积分数为33.55×10-9,略高于冬季的25.44×10-9;夜间NO2和SO2体积分数比白天高,并且NO2呈明显的单峰单谷型分布,O3也呈单峰型但峰值出现在白天。NO2、SO2体积分数存在着明显的"假日效应",假日比非假日低,周五高于假日和非假日;但O3体积分数没有明显的假日效应。降水对SO2有明显的清除作用,但对NO2的清除作用不明显。与风向对比发现,夏季高体积分数的NO2、SO2都受到NW、WNW风的影响,冬季则分别受NE和SW、SSW风的影响;而O3受风向的影响较复杂,与局地光化学反应有关。This paper studies NO2, SO2, and 03 at Linan in summer and winter of 2003 and 2004. Results show that the mean volume fractions of NO2 and SO2 are 19.48 ×10^-9 and 35.74×10^-9 in winter,respectively,which are higher than those in summer（4.81 × 10^-9 and 8.12× 10^-9, respectively）. The mean volume fractions of O3 is 33.55 × 10^-9 in summer, which is higher than that in winter （25.44 × 10^-9）. The volume fractions of NO2 and SO2 during the daytime are lower than those during the nighttime. The diurnal variation of NO2 volume fraction shows the single valley and single peak dis- tribution with its peak during the nighttime. The diurnal variation of O3 volume fraction is similar to NO2, but its peak appears during the daytime. The volume fractions of NO2 and SO2 show an obvious ＂Holiday Effect＂, and are obviously lower during weekends than those during weekdays, with the highest on Fridays. The volume fraction of 03 does not have an obvious ＂Holiday Effect＂. The wet removal efficiency of precipitation to SO2 is more obvious than to NO2. By contrast with the different wind directions, the higher volume fractions of NO2 and SO2 are affected by NW and WNW winds in summer, while by NE, SW and SSW winds in winter. The influence of wind direction on the ozone is complex, which is relevant to local photochemical reactions.

关 键 词：二氧化氮 二氧化硫 臭氧 假日效应 降水 

分 类 号：P402[天文地球—大气物理学与大气环境]