六氟丙烯齐聚物类表面活性剂合成及性能研究进展  

Research Progress on Performance and Synthesis of Surfactants Based on Hexafluoropropene Oligomers

作　　者：郑土才[1] 赵颖俊[1] 雷志刚 周强 王树华 

机构地区：[1]衢州学院化学与材料工程学院,324000 [2]巨化集团技术中心,浙江衢州324004

出　　处：《化工生产与技术》2012年第6期6-11,共6页Chemical Production and Technology

基　　金：衢州市科技计划项目(20091036);浙江省科技厅公益项目(2010C31129);2012年校级大学生项目

摘　　要：介绍了六氟丙烯齐聚物(主要为二聚体和三聚体,又名全氟己烯和全氟壬烯)衍生的表面活性剂的特性、用途及主要合成方法,叙述了六氟丙烯齐聚物衍生的表面活性剂合成、表面性能和应用进展。认为分子中含有2个亲水基团和2个亲油链的双子表面活性剂具有形成胶束能力强、临界胶束浓度低、降低表面张力的效率高、克拉夫特点低、水溶性好,与其他表面活性剂的配伍性好等诸多优点,具有较好地发展前景。This paper introduced the characteristics,purposes and main synthesis methods of surfactant based on hexafluoropropene oligomers(mainly dimer and trimer,alternate names were perfluorohexene and perfluorononene),related the synthesis,surface property and application progress of surfactant derived from hexafluoropropene oligomers.The Gemini surfactant with two hydrophilic groups and two lipophilic chains had advantages of low micelle concentration,high effect to reduce surface tension,low Krafft point,good water solubility,and good compatibility with other surfactant,which had good development prospect.

关 键 词：六氟丙烯齐聚物 全氟己烯 全氟壬烯 氟表面活性剂 

分 类 号：TQ423[化学工程]