光散射/荧光比率法测定全氟辛烷磺酸  被引量:3

Determination of Perfluorooctane Sulfonate by Light Scattering-Fluorescence Ratio Method

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作  者:谭克俊[1] 吴飞[1] 代旭[1] 郑莉[1] 

机构地区:[1]发光与实时分析教育部重点实验室,西南大学化学化工学院,重庆400715

出  处:《应用化学》2013年第2期220-224,共5页Chinese Journal of Applied Chemistry

基  金:国家自然科学基金(20877063);西南大学大型仪器设备开放基金(201133)资助项目

摘  要:在pH=1.81的Britton-Robinson(BR)缓冲溶液中,全氟辛烷磺酸(PFOS)与罗丹明B(RhB)通过静电引力和疏水作用使RhB的光散射增强,荧光发生猝灭。利用在普通荧光光度计上单次扫描获得的340 nm处的光散射强度(I340)与596 nm处的荧光强度(F596)之比,建立了测定PFOS的光散射/荧光比率法,检出限(3σ)为17 nmol/L。方法用于环境水样中PFOS的测定,RSD≤4.2%。Perfluorooctane sulfonate (PFOS) can quench the fluorescence of rhodamine B (RhB) in pH = 1.81 Britton-Robinson(BR) buffer solution, and results in light scattering enhancement by electrostatic forces and hydrophobic interactions. In this work, a light scattering-fluorescence ratio method of PFOS was established with a common spectrofluorometer by measuring the light emission signals through one scanning, out of which a ratio of the intensity of light scattering at 340 nm to that of fluorescence at 596 nm could be obtained. The linear range is from 0. 17 to 10. 0 p.mol/L, and the limit of detection(3σ) is 17 nmol/L. The method has been applied to the determination of PFOS in the environmental samples with RSD≤4. 2%.

关 键 词:全氟辛烷磺酸 罗丹明B 散射 荧光比率法 

分 类 号:O657.3[理学—分析化学]

 

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