介孔Co-Al_2O_3催化剂上甲烷部分氧化制合成气  

Partial oxidation of methane to syngas over mesoporous Co‐Al_2O_3 catalysts

作　　者：刘瑞艳[1] 杨美华[1] 黄传敬[1] 翁维正[1] 万惠霖[1] 

机构地区：[1]厦门大学化学化工学院化学系,固体表面物理化学国家重点实验室,福建厦门361005

出　　处：《催化学报》2013年第1期146-151,共6页

基　　金：supported by the National Basic Research Program of China (973 Program; 2010CB732303);the National Natural Science Foundation of China (21173173; 21073148; 21033006);the Program for Innovative Research Team of the Ministry of Education of China (IRT1036);the Key Scientific Project of Fujian Province; China (2009HZ0002‐1)~~

摘　　要：采用一锅法制备了介孔Co-Al2O3催化剂,并首次用于甲烷部分氧化制合成气反应. 结果表明,与普通浸渍法相比,一锅法制备的Co-Al2O3催化剂表现出更为优异的催化性能. 合成的介孔Co-Al2O3催化剂具有大的比表面积和孔体积,以及规整有序的六方介孔孔道,Co物种高度分散,从而导致还原后高的金属分散度,而介孔孔道对金属纳米颗粒的约束作用可有效增强金属的抗烧结能力.Mesoporous Co‐Al2O3 catalysts were prepared by one‐pot synthesis and,for the first time,used in the partial oxidation of methane to synthesis gas.Compared with the catalysts prepared by impregnation methods,the catalysts prepared by one‐pot synthesis showed superior catalytic performance for this reaction.The results showed that mesoporous Co‐Al2O3 catalysts have high surface areas,large pore volumes,and an ordered hexagonal mesostructure.In the catalysts,Co species are highly dispersed,resulting in high dispersion of the metal after reduction.A confinement effect,provided by the mesopores,on metal nanoparticles could effectively enhance resistance to metal sintering.

关 键 词：甲烷 部分氧化 合成气 钴 氧化铝 介孔 

分 类 号：TE665.3[石油与天然气工程—油气加工工程]