微波消解-原子荧光光谱法测定皮革中砷和汞  

Determination of Arsenic and Mercury in Leather by Microwave Digestion-Atomic Fluorescence Spectrometry

作　　者：刘正华[1] 陈新焕[1] 戴建平[1] 吕小园[1] 杨万彪[1] 陈练[1] 

机构地区：[1]湖南出入境检验检疫局,湖南长沙410004

出　　处：《分析科学学报》2013年第1期117-120,共4页Journal of Analytical Science

基　　金：国家认证认可监督管理委员会检验检疫行业标准制订项目(No.2008B150)

摘　　要：建立了皮革中砷和汞的微波消解-原子荧光光谱测定方法。在优化的实验条件下,砷、汞含量分别在0.60～150ng/mL和0.10～20ng/mL范围内线性良好。砷、汞检出限分别为0.22ng/mL和0.04ng/mL。方法测定砷的回收率为96.0%～104%,汞的回收率为95.0%～110%。方法准确、灵敏、快速、可应用于皮革样品中砷和汞的同时测定。A method for the determination of arsenic and mercury in leather by microwave digestion and atomic fluorescence spectrometry has been developed. Under the optimized experimental conditions, the linear range for arsenic was between 0. 60 and 150 ng/mL, and for mercury 0. 10- 20 ng/mL, with detection limits of 0.22 104%, 95. 0G and 11 operation. It can be appl Keywords： Microwave d ng/mL and 0.04 ng/mL,respectively. The recoveries were between 96.0% and 0%, respectively. The method features high accuracy, sensitivity and simple ied for determination of arsenic and mercury in real leather samples.

关 键 词：微波消解 原子荧光光谱法 皮革 砷 汞 

分 类 号：O657.31[理学—分析化学]