酸碱改性HZSM-5分子筛上甲醇制取均四甲苯的研究  

Synthesis of durene from methanol over alkali and acid modified HZSM-5

作　　者：肖何[1,2] 高俊华[1] 胡津仙[1] 章斌[1] 刘平[1] 张侃[1] 

机构地区：[1]中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001 [2]中国科学院大学,北京100049

出　　处：《燃料化学学报》2013年第1期102-109,共8页Journal of Fuel Chemistry and Technology

摘　　要：对HZSM-5分子筛进行"酸碱两步改性",制备得到了H(0.2)-Na-ZSM-5、H(0.5)-Na-ZSM-5、H(0.2)-K-ZSM-5和H(0.5)-K-ZSM-5四种催化剂。通过XRD、NH3-TPD、ICP、FT-IR与Py-IR方法对催化剂进行表征,并在连续流动固定床反应装置上对催化剂进行评价。实验结果表明,H(0.2)-K-ZSM-5催化剂由于其孔径变大、弱的B酸量增多,从而提高了均四甲苯的选择性。Alkali and acid modified HZSM-5 molecular sieves were prepared through treating with different alkali solutions together with nitric acid of different concentrations; four catalysts, i.e. H （0.2） -Na-ZSM-5, H （ 0.5 ） -Na-ZSM-5, H （0.2） -K-ZSM-5 and H （ 0.5 ） -K-ZSM-5 were obtained. These catalysts were characterized by means of XRD, NH3-TPD, ICP, FT-IR and Py-IR; their performance in the synthesis of durene from methanol was investigated in a fixed-bed down-flow reactor. The results showed that the highest selectivity to durene for methanol aromatization is achieved over the H（0.2）-K-ZSM-5 catalyst, which should be ascribed to its large pore size and abundant weak B acid sites arising from the alkali and acid modification.

关 键 词：HZSM-5 甲醇 均四甲苯 碱处理 酸处理 

分 类 号：O643[理学—物理化学]