絮体性质对纳滤膜污染的影响  

Effect of floc characteristics on nanofiltration membrane fouling

作　　者：于洋[1] 赵长伟[1] 王艳贵[1,2] 范卫红[1,3] 栾兆坤[1] 

机构地区：[1]中国科学院生态环境研究中心环境水质学国家重点实验室,北京100085 [2]中国矿业大学化学与环境工程学院,北京100083 [3]北京化工大学生命科学与技术学院,北京100029

出　　处：《环境工程学报》2013年第2期427-432,共6页Chinese Journal of Environmental Engineering

基　　金：国家自然科学基金资助项目(21176245;50978245);国家科技支撑计划课题(2012BAJ25B02;2012BAJ25B06);国家水体污染控制与治理科技重大专项(2008ZX07101-006)

摘　　要：混凝过程产生的絮体会对后续膜过滤性能产生一定的影响。实验中利用激光粒度仪研究2种混凝剂(AlCl3和PAC)在不同投加量下的絮体性质,混凝出水(不经过沉淀)直接进入纳滤膜(NF270)装置进行过滤实验。研究表明,投加量低(<0.20 mmol/L)的情况下,混凝出水反而使纳滤通量衰减发生恶化,随着投加量的增加,纳滤膜通量衰减得到有效的减缓。直接过滤腐殖酸(HA)的膜通量衰减(J/J0)为0.65,投加量为0.50 mmol/L时,AlCl3和PAC 2种混凝剂产生的通量衰减(J/J0)分别为0.78和0.75。滤饼层阻力受到絮体尺寸的影响较大,絮体尺寸越大,形成的滤饼层透水性更好。通过污染模型分析,混凝出水的纳滤膜污染机理主要是滤饼层阻力。Flocs formed by coagulation process will also affect the performance of membrane filtration. Floc characteristics of coagulants-conventional A1 salt （A1Cl3 ） and polyaluminum chloride （PAC） under different dosages were investigated by using a laser diffraction instrument. The results showed that membrane flux decline was deteriorated less than 0.20 mmoi/L dosages. With the dosages increasing, membrane flux decline decreased significantly. The flux decline （J/Jo） with only humic acid （HA） was 0.65. Adding 0.50 mmol/L A1C13 and PAC coagulants, the flux declined 0.78 and 0.75, respectively. Cake resistance was more obviously affected by floc size. The bigger floc size is, the better permeability of cake is. The mechanism of nanofiltration membrane fouling was mainly pore blocking by fouling model analysis.

关 键 词：混凝 絮体性质 纳滤 膜污染 

分 类 号：X520.5[环境科学与工程—环境工程]