Highly Substituted Cyclopentenes Formation via a Stereose- lective Tandem CDC Reaction and Cyclization  

作　　者：Li Yi Cao Li Luo Xiaoyan Deng Weiping 

机构地区：[1]Shanghai Key Laboratory of New Drug Design & School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China

出　　处：《Chinese Journal of Chemistry》2012年第12期2834-2838,共5页中国化学（英文版）

基　　金：supported by the Natural Science Foundation of China （No. 20972047）, the ‘Shu Guang＇ project of Shanghai Municipal Education Commission, Shanghai Education Development Foundation （No. 09SG28）, the Fundamental Research Funds for the Central Universities and the Shanghai Committee of Science and Technology （No. 11DZ2260600）.

摘　　要：A facile iron-catalyzed C（sp3）-C（sp2） bond formation through DDQ-mediated cross-dehydrogenative homo-coupling of （E）-1,2-diarylprop-1-enes for the synthesis of highly aryl-substituted cyclopentenes has been developed.A facile iron-catalyzed C（sp3）-C（sp2） bond formation through DDQ-mediated cross-dehydrogenative homo-coupling of （E）-1,2-diarylprop-1-enes for the synthesis of highly aryl-substituted cyclopentenes has been developed.

关 键 词：cross-dehydrogenative coupling highly awl-substituted cyclopentenes 

分 类 号：TQ224.14[化学工程—有机化工] TP311[自动化与计算机技术—计算机软件与理论]