A New Luminescent Complex Cd(Ⅱ)-xanthene-9-carboxylate: [Cd(L)_2(H_2O)]_n  

作　　者：尚洁 吴小园 王飞 杨文斌 余荣民 卢灿忠 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [2]Graduate School of Chinese Academy of Sciences [3]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2013年第1期96-100,共5页结构化学（英文）

基　　金：Supported by the 973 key program of the MOST(2010CB933501,2012CB821705);the Chinese Academy of Sciences(KJCX2-YW-319,KJCX2-EW-H01);the National Natural Science Foundation of China;the Natural Science Foundation of Fujian Province(2007HZ0001-1,2009HZ0004-1,2009HZ0005-1,2009HZ0006-1,2006L2005)

摘　　要：A new luminescent Cd（Ⅱ） coordination polymer, [Cd（L）2（H2O）]n 1 （HL = xan-thene-9-carboxylic acid）, was synthesized hydrothermally and characterized by satisfactory elemental analysis, FT-IR spectra and single-crystal X-ray diffraction. The crystal is of orthorhombic system, space group P212121 with a = 6.4548（4）, b = 13.0876（12）, c = 27.466（2）, V = 2320.3（3）3, C28H20CdO7, Mr = 580.84, Z = 4, Dc = 1.663 g/cm3, F（000） = 1168, μ = 0.990 mm-1, Flack parameter = 0.00（2）, the final R = 0.0296 and wR = 0.0691 for 5301 observed reflections （I 2σ（I））. 1 features a one-dimensional （1D） carboxylate oxygen-bridged inorganic chain, which is further connected by intermolecular hydrogen bonds into a three-dimensional （3D） framework. Moreover, compound 1 exhibits strong photoluminescence in the solid state at room temperature.A new luminescent Cd（Ⅱ） coordination polymer, [Cd（L）2（H2O）]n 1 （HL = xan-thene-9-carboxylic acid）, was synthesized hydrothermally and characterized by satisfactory elemental analysis, FT-IR spectra and single-crystal X-ray diffraction. The crystal is of orthorhombic system, space group P212121 with a = 6.4548（4）, b = 13.0876（12）, c = 27.466（2）, V = 2320.3（3）3, C28H20CdO7, Mr = 580.84, Z = 4, Dc = 1.663 g/cm3, F（000） = 1168, μ = 0.990 mm-1, Flack parameter = 0.00（2）, the final R = 0.0296 and wR = 0.0691 for 5301 observed reflections （I 2σ（I））. 1 features a one-dimensional （1D） carboxylate oxygen-bridged inorganic chain, which is further connected by intermolecular hydrogen bonds into a three-dimensional （3D） framework. Moreover, compound 1 exhibits strong photoluminescence in the solid state at room temperature.

关 键 词：CADMIUM hydrothermal synthesis supramolecular structure photoluminescence 

分 类 号：O627.2[理学—有机化学]