Subsolidus Phase Relations in the ZnO-BaO-V_2O_5 System  

作　　者：郑萌 吕佩文 陈达贵 颜峰波 黄丰 

机构地区：[1]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [2]Graduate School of Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2013年第1期106-112,共7页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China(20971123,51002153,21007070,51102232,61106004 and 21103191);the National Basic Research Program of China(973Program,2010CB933501);the Natural Science Foundation of Fujian Province(2010J01054,2010J06006 and 2010J05038);the NSF of Outstanding Youth Fund(21125730)

摘　　要：The subsolidus phase relations of the ZnO-BaO-V2O5 ternary systems were investigated by means of X-ray diffraction analysis. There are three ternary compounds, nine binary compounds and sixteen 3-phase regions found in this system. The crystal structure of the ternary compound Ba2ZnV2O8 was refined by Rietveld profile fitting method and the powder diffraction pattern is given. A new ternary compound Ba3.4Zn0.8V4O14.2 has been found by the powder diffraction pattern.The subsolidus phase relations of the ZnO-BaO-V2O5 ternary systems were investigated by means of X-ray diffraction analysis. There are three ternary compounds, nine binary compounds and sixteen 3-phase regions found in this system. The crystal structure of the ternary compound Ba2ZnV2O8 was refined by Rietveld profile fitting method and the powder diffraction pattern is given. A new ternary compound Ba3.4Zn0.8V4O14.2 has been found by the powder diffraction pattern.

关 键 词：ZnO-BaO-V2O5 system phase diagram ZNO X-ray diffraction 

分 类 号：O614.241[理学—无机化学]