Triton X-114存在下镉试剂分光光度法测定环境水样中的镉  

Spectrophotometric Determination of Cd(Ⅱ) in Environmental Water Samples with Cadion in the Presence of Triton X-114 Surface Active Agent

作　　者：高琳[1,2] 陈圣洁[1,2] 陈芳[1,2] 

机构地区：[1]光电化学材料与器件省部共建教育部重点实验室江汉大学,湖北武汉430056 [2]江汉大学化学与环境工程学院,湖北武汉430056

出　　处：《岩矿测试》2013年第1期114-118,共5页Rock and Mineral Analysis

基　　金：国家自然科学基金项目(21107033);湖北省教育厅科学技术研究项目(B20114507);武汉市教育局武汉市属高校科研课题(2009K006)

摘　　要：及时监测环境水中的镉含量是预防和治理镉污染的前提,采用分光光度法测定镉具有简便、迅速、易普及等特点,然而较低的灵敏度限制了该方法的应用。本文通过选用表面活性剂Triton X-114为增敏剂,有效地提高了镉试剂分光光度法测定镉离子的灵敏度。研究结果表明,在KOH溶液中,Triton X-114存在下,镉试剂与镉离子生成橙红色络合物,显色物质最大吸收峰为470 nm,镉离子含量在0～10μg/25 mL范围内符合比尔定律,表观摩尔吸光系数达到1.25×105L/(mol.cm),检测限低至5.0μg/L。与Triton X-100以及其他表面活性剂相比,Triton X-114的应用能显著提高镉试剂光度法测定镉的吸光度,表观摩尔吸光系数最高可增加49%,检测限也能够降低近50%,并且分析方法简便迅速,易普及,可应用于环境水以及工业废水中微量或痕量镉的直接测定。It is vital to monitor the cadmium （Cd） content in environmental water over time, as it is a prerequisite to prevent and control Cd contamination. Spectrophotometric determination of Cd was simple, rapid and well established. However, low sensitivity limits the application of Spectrophotometry to determine Cd content in environmental water samples. The sensitivity of Cd can be significantly improved for Speetrophotometry by using the surface active agent Triton X-114. In a KOH medium, Cd ions react with eadion to form orange complex. In tests, the maximum absorption and molar absorptivity for the orange complex were 470 nm and 1.25 ×105 L/（ tool · era）, respectively. Beer＇s law was obeyed for 0 - 10 μg of Cd in 25 mL of solution. The detection limit was 5.0 μg/L. Compared with Triton X-100 and other surface active agents, Triton X-114 can increase maximum of 49% to the molar absorption coefficient and reduced about 50% of the detection limit. This method is simple, fast and suitable to determine directly major or trace Cd in environmental water and industrial wastewater.

关 键 词：环境水样 镉 镉试剂 TRITON X-114 表面活性剂 分光光度法 

分 类 号：P641[天文地球—地质矿产勘探] O614.242[天文地球—地质学]