Metal complex with terpyrindine derivative ligand as highly selective colorimetric sensor for iron(Ⅲ)  

作　　者：Peng Wang Taka-aki Okamura Hong-Ping Zhou Wei-Yin Sun Yu-Peng Tian 

机构地区：[1]Coordination Chemistry Institute,State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing National Laboratory of Microstructures,Nanjing University [2]Department of Macromolecular Science,Graduate School of Science,Osaka University [3]Department of Chemistry,Anhui Province Key Laboratory of Functional Inorganic Materials Chemistry,Anhui University

出　　处：《Chinese Chemical Letters》2013年第1期20-22,共3页中国化学快报（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(Nos.91122001 and 21021062);the National Basic Research Program of China(No. 2010CB923303)

摘　　要：A new metal complex [MnL2]（NO3）2.CH3CN （1） was synthesized by reaction of 4＇-4-（],2,4-triazol-]-yl）- phenyl-2,2＇：6＇,2＂-terpyridine （L） with manganese nitrate. The structure of the complex was determined by X-ray crystallography. The results of UV-vis studies showed that the complex exhibits colorimetric sensing ability for Fe3~, which can be observed by naked eye.A new metal complex [MnL2]（NO3）2.CH3CN （1） was synthesized by reaction of 4＇-4-（],2,4-triazol-]-yl）- phenyl-2,2＇：6＇,2＂-terpyridine （L） with manganese nitrate. The structure of the complex was determined by X-ray crystallography. The results of UV-vis studies showed that the complex exhibits colorimetric sensing ability for Fe3~, which can be observed by naked eye.

关 键 词：Terpyridine derivative ligandMn（ll） complexCrystal structureColorimetric sensor 

分 类 号：O641.4[理学—物理化学] TP212[理学—化学]