四碱式硫酸铅的制备及其性能  

The preparation and performance of tetrabasic lead sulphate

作　　者：张靖佳[1] 邬冰[1] 王振波[2,3] 佘建中 臧宁 

机构地区：[1]哈尔滨师范大学化学化工学院,黑龙江哈尔滨150025 [2]哈尔滨工业大学化工学院,黑龙江哈尔滨150001 [3]浙江长兴绿色动力能源科技有限公司,浙江长兴313100

出　　处：《蓄电池》2013年第1期37-42,共6页Chinese LABAT Man

基　　金：哈尔滨师范大学博士启动基金(KGB200812);黑龙江省自然科学基金(B201002)

摘　　要：随着通讯产业和电动汽车的迅猛发展,期待出现具有更高比能量和比功率以及更长循环寿命的铅酸蓄电池。为了解决铅酸蓄电池早期容量损失问题,在正极铅膏中添加四碱式硫酸铅(4BS)作为添加剂已被证实是防止蓄电池早期容量损失的有效措施之一。本文评述了正极铅膏添加剂四碱式硫酸铅的制备方法,介绍了其结构及性能,展望了4BS在铅酸蓄电池中的应用。In recent years, with the rapid development of communication and electric car industries, looking forward to appear the lead-acid battery with the higher specific energy and power and the it was longer life cycle. In order to solve the premature capacity loss of lead-acid battery, the tetrabasic lead sulphate （4BS） was added into the positive lead paste as an additive. In this paper, the performance of tetrabasic lead sulphate as additive of the positive lead paste was discussed. The structure and performance of tetrabasic lead sulphate was introduced. We also give an overview of the future development direction of the tetrabasic lead sulphate used for lead-acid battery in the end of this paper.

关 键 词：铅酸蓄电池 四碱式硫酸铅 早期容量损失 正极添加剂 

分 类 号：TM912.1[电气工程—电力电子与电力传动]