不同催化剂对生物质半焦低温气化效果的影响  

Effects of different catalysts on steam gasification of biomass char at low temperature

作　　者：俞元元[1] 肖军[1] 沈来宏[1] 杜玉照[1] 

机构地区：[1]东南大学热能工程研究所能源热转换及其过程测控教育部重点实验室,南京210096

出　　处：《农业工程学报》2013年第3期190-197,共8页Transactions of the Chinese Society of Agricultural Engineering

基　　金：国家重点基础研究发展规划(973计划;2010CB732206)

摘　　要：生物质气化技术是将低品位的生物质能转换成高品位能源的有效途径。该文以稻壳和麦秸半焦为试验对象,进行了低温下生物质半焦的水蒸气气化试验,研究了浸渍法制备的碱金属催化剂和气化温度对生物质半焦气化行为的影响。结果显示,对于稻壳半焦气化而言,相同负载量的K基催化剂的催化效果明显优于Na基催化剂,相比非催化时稻壳半焦的碳转化率分别提高了18.2%和13.5%,差异明显。增加K2CO3负载量有利于半焦气化反应的进行,但负载量不宜超过30%。不同的煅烧温度,催化剂的活性组分存在形式有较大差别,负载量为30%的K基催化剂在800℃煅烧后具有最佳的催化效果。相同条件下,麦秸半焦的气体产率和碳转化率均较高,在700℃下添加该催化剂时分别达到130.0mol/kg和95.9%,相比非催化时分别提高了57.0%和34.1%。随着温度的降低,气体产率和碳转化率均明显下降,该文催化条件下的半焦气化温度不宜低于700℃。研究结果可为生物质低温气化高效催化剂的选择提供理论依据。The low-temperature catalytic gasification of biomass is a promising technology for hydrogen production from the energy point of view due to its relatively low heat input. And it has attracted the worldwide interests. However, the lower char conversion efficiency and higher tar yield at low-temperature are unsolved problems to the technical application of low-temperature catalytic gasification. In order to overcome these issues, numerous researches are being focused on the catalyst development. As the studies concerning catalytic gasification of biomass char under relatively low temperature （T≤750℃） are fairly limited, catalytic gasification of two biomass char samples, rice husk and wheat straw, were investigated at relatively low temperature in this paper. The impregnated alkali metal catalysts were prepared in this study. In which, Al2O3 was used as carrier of the catalyst, and potassium carbonate and sodium carbonate were used as active ingredient, respectively. In addition, the catalyst components were detected by X-ray diffraction analysis （XRD）. Using the prepared catalysts, catalytic steam gasification of biomass char was carried out in a lab-scale fluidized bed reactor at the temperature between 600 and 700℃ ℃ to investigate the performance of catalysts. And the effects of catalyst parameters including active ingredient, ingredient contents and calcination temperature, and gasification temperature on the behavior of char gasification were also studied. The results revealed that both potassium based catalyst and sodium based one have significant catalytic action on biomass char conversion. Moreover, potassium based catalyst exhibited better catalytic performance than sodium based one with the same content of active component in rice husk char gasification process. Compared with non-catalytic rice husk char gasification, carbon conversion efficiency was increased by 18.2% and 13.5% using 30KAl（600） and 30NaAl（600）, respectively. Increasing K2CO3 content was beneficial to improving c

关 键 词：催化剂 温度 能源 生物质半焦 气化 

分 类 号：TK6[动力工程及工程热物理—生物能]