电解氟化在无机氟化物制备中的应用  

Application of electrolytic fluorination in inorganic fluoride production

作　　者：赵启泰 赵建轩 

机构地区：[1]核工业理化工程研究院,天津300180 [2]天津英伦研究开发中心

出　　处：《无机盐工业》2013年第3期1-4,共4页Inorganic Chemicals Industry

摘　　要：电解氟化是制备多种有机氟化物的重要方法之一,依据其工艺过程和机理,它也是制备某些无机氟化物的重要方法。介绍了电解氟化的工艺过程和反应机理,并提出电解氟化在无机氟化物制备中应用的方法。提出了机理的新概念——弱电场自由基反应机理。Electrolytic fluorination is one of important production methods of organic fluorides.Based on its technological pro- cess and mechanism, it is also an important way to produce some inorganic fluorides.Technological process and reaction mechanism of electrolytic fluorination were introduced.Application methods for electrolytic fluorination in inorganic fluoride production were provided.Finally, a new conception about free radical reaction mechanism of weak electric field was put forward.

关 键 词：电解氟化 电化学氟化 无机氟化物 反应机理 

分 类 号：TQ124.3[化学工程—无机化工]