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作 者:黄奇波[1,2] 覃小群[1,2] 唐萍萍[1,2] 刘朋雨[1]
机构地区:[1]中国地质科学院岩溶地质研究所,广西桂林541004 [2]国土资源部广西壮族自治区岩溶动力学重点实验室,广西桂林541004
出 处:《地球化学》2013年第1期64-72,共9页Geochimica
基 金:中国地质调查项目(1212011087121);中国地质科学院岩溶地质研究所所控项目(2012013)
摘 要:对桂林地区地下河水、岩溶大泉中的δ13CDIC、δ18O及Ca2+、Sr2+含量进行了测试分析。结果表明,地下河水的δ13CDIC值范围为–15.99‰~–12.29‰,平均值为(–14.03±1.15)‰;δ18O值范围为–6.63‰~–5.78‰,平均值为(–6.24±0.24)‰。岩溶大泉的δ13CDIC值范围为–15.26‰~–9.22‰,平均值为(–12.05±1.57)‰;δ18O值范围为–6.97‰~–3.19‰,平均值为(–5.68±0.97)‰。岩溶大泉的δ13CDIC值、δ18O值比地下河水的分别偏重1.98‰和0.56‰。通过分析发现,水的循环方式引起了不同类型地下水的同位素差异,地下河以管道流的形式进行循环,循环速度快,水岩作用时间短,碳酸盐岩碳的贡献相对较少;同时,出口处水所经历的蒸发作用时间也短,水的δ18O值偏轻。岩溶大泉以裂隙流的形式进行循环,循环速度慢,水岩作用时间长,碳酸盐岩碳的贡献相对较多;泉口处水所经历的蒸发作用时间也长,水的δ18O值偏重。Sr/Ca值与δ13CDIC值具有正相关关系,而与δ18O值的相关性差。这意味着δ13CDIC值与Sr/Ca值一样,可以在一定程度上反映出地下水的径流条件。After sampling and analyzing carbon isotope (δ13CDIC) and oxygen isotope (δ18O) in subterranean river and large karst springs in Guilin, Guangxi Zhuang Autonomous Region, southwest China, we found: (a) the carbon isotopic (δ13CDIC) values in subterranean river ranged from -15.99%o to -12.29%o, with a mean value of (-14.03 ± 1.15)%o; and oxygen isotope (δ18O) values ranged from -6.63%0 to -5.64%0, with a mean value of (-6.24 ± 0.24)%0; the carbon isotopic (δ13CDIC) values in large karst springs ranged from -15.26%o to -9.22%0, with a mean value of (-12.05 ± 1.57)%o; and oxygen isotope (δ18O) values ranged from -6.97%0 to -3.19%o, with a mean value of (-5.68 ± 0.97)%o; (b) the carbon isotopic (δ13CDIC) and oxygen isotope (δ18O) values in subterranean river were generally lower than those in large karst springs; (c) the water circulation caused the isotopic differences in difference types of water. In subterranean river, water is in the form of conduit flow, with a fast rate of cycle and a short time of water-rock interaction. Therefore, little heavy carbon isotope (δ13CD±c) came from carbonatite rock to the water, with a short time of distillation process, so the carbon isotope (δ13CDIC) is light. In contrast, water in large karst springs is fissure flow, with a slow circulation rate and a long water-rock time, which lead more heavycarbon isotope came from carbonatite rock to the water, furthermore, its distillation process time is longer, so the carbon isotope (±13CDIC) is heavy. ±13CDIC valued with the same situation as Sr/Ca, it could reflect the run-off condition of groundwater to some degree.
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