城市生活垃圾可生物降解组分动态水解研究  

Dynamic Hydrolysis of Organic Fraction of Municipal Solid Waste

作　　者：何品晶[1,2] 张宗兴[1,2] 吴铎[1,2] 吕凡[1,2] 

机构地区：[1]同济大学环境科学与工程学院,上海200092 [2]同济大学固体废物处理与资源化研究所,上海200092

出　　处：《同济大学学报（自然科学版）》2013年第2期228-233,共6页Journal of Tongji University:Natural Science

基　　金：国家"八六三"高技术研究发展计划(2008AA062401);上海市优秀学科带头人计划(10XD1404200);上海市浦江人才计划(11PJ1409200);上海市科技创新行动计划(12231202003)

摘　　要：通过96h无置换动态水解批式实验和不同缓冲液置换频率动态水解批式实验,研究破碎预处理、翻转、甲烷化出水和不同时间间隔置换操作对于城市生活垃圾可生物降解组分(OFMSW)厌氧消化水解过程的影响.结果表明:翻转可使OFMSW的动态水解效率最高达到42.7%(未破碎甲烷化出水缓冲液工况),而不翻转时仅有22.3%;与蒸馏水相比,未破碎预处理工况下,甲烷化出水可使OFMSW的水解效率提高40.6%;但破碎预处理之后,仅提高了3.6%,说明对OFMSW进行破碎预处理不会显著提高水解效率,反而增加了破碎能耗;缓冲液置换操作一定程度上解除了高浓度有机酸的产物抑制;不同置换频率工况相比,虽然每24h和每48h置换的工况比每12h置换的工况所得到的OFMSW减重率分别高出11.5%和40.7%,但能耗相应增加了100%和300%,因此,缓冲液置换频率以12h为最佳.Batch experiments of dynamic hydrolysis at different hydrolysate replacement frequencies in 96 h were conducted to evaluate the effects on anaerobic hydrolysis of organic fraction of municipal solid waste （OFMSW） caused by homogenization pretreatment, overturn, methanogenic effluent and hydrolysate replacement frequency （12 h, 24 h, 48 h, 96 h）. Results show that the operation of overturn mixing improves the hydrolysis efficiency of OFMSW by 42.7 % at most which happenes in the methanogenic-buffered scenario without homogenization, and the hydrolysis efficiency in the scenario without the operation of overturn mixing can only be 22. 3%. Compared with the distilled water, the hydrolysis rate of un-homogenized OFMSW increases by 40.6% with methanogenic effluent as buffer. However, the increment is only 3.6% in the hydrolysis of homogenized OFMSW, which indicates that the homogenization has not significantly improved the hydrolysis efficiency, but increased the energy consumption. Hydrolysate replacement to some extent eliminates the inhibition of organic acid. The increments of weight loss by 11.4 % and 40.7% are accomplished in the scenarios with hydrolysate replacement frequencies of 24 h ·run^-1 and 48 h·run^-1, compared with that of 12 h·run^-1. However, the energy consumption increases by 100% and 300%, respectively, suggesting that the hydrolysate replacement frequency of 12 h·run^-1 is optimal.

关 键 词：城市生活垃圾 动态水解 缓冲液置换频率 能耗 减重率 

分 类 号：X705[环境科学与工程—环境工程]