Distribution characteristics and source identification of polychlorinated dibenzo-p-dioxin and dibenzofurans,and dioxin-like polychlorinated biphenyls in the waters from River Kanzaki,running through Osaka urban area,Japan  

作　　者：Masao Kishida 

机构地区：[1]Research Institute of Environment,Agriculture,and Fisheries,Osaka Prefecture,1-3-62 Nakamichi,Higashinari-ku,Osaka 537-0025,Japan [2]Commerce and Industry Promotion Office,Department of Commerce,Industry and Labor,Osaka Prefectural Government,Sakishima Building,1-14-16 Nankohkita,Suminoe-ku,Osaka 559-8555,Japan

出　　处：《Journal of Environmental Sciences》2013年第3期441-451,共11页环境科学学报（英文版）

摘　　要：This is the first to elucidate the distribution and sources of polychlorinated dibenzo-p-dioxins and dibenzofurans （PCDD/PCDFs）,and dioxin-like polychlorinated biphenyls in the waters from Kanzaki River,which is one of the most heavily polluted rivers in Japan.The World Health Organization （WHO）-toxic equivalent quantities （TEQs） in waters from the mainstream exceeded the Japanese environmental standard （1.0 pg-TEQ/L）.The PCDD/PCDFs were dominated by highly chlorinated DFs,which predominantly contributed to the WHO-TEQs,suggesting that the main causes would be the incineration-related wastes.To find the sources,the dioxin congener concentrations in water and sediment samples from its tributary small waterways were determined.Abnormally high WHO-TEQs were detected in a water （50 pg-TEQ/L） and a sediment sample （41,000 ng-TEQ/kg dry weight） near the industrial solid waste incinerators （ISWIs）.The PCDD/PCDF characteristics agreed well with those of the incinerator-related wastes as seen in the mainstream.These facts indicate that the dioxin pollution in the mainstream could be largely related to the industrial wastes from the ISWIs.Here,a TEQ apportionment method was used to understand the contribution of the pyrogenic sources to the WHO-TEQs.The average contribution ratios of the pyrogenic sources to WHO-TEQs were more than 80% for river waters from the mainstream,indicating that the elevated WHO-TEQs in the mainstream had been largely caused by the ISWIs.This is the first to elucidate the distribution and sources of polychlorinated dibenzo-p-dioxins and dibenzofurans （PCDD/PCDFs）,and dioxin-like polychlorinated biphenyls in the waters from Kanzaki River,which is one of the most heavily polluted rivers in Japan.The World Health Organization （WHO）-toxic equivalent quantities （TEQs） in waters from the mainstream exceeded the Japanese environmental standard （1.0 pg-TEQ/L）.The PCDD/PCDFs were dominated by highly chlorinated DFs,which predominantly contributed to the WHO-TEQs,suggesting that the main causes would be the incineration-related wastes.To find the sources,the dioxin congener concentrations in water and sediment samples from its tributary small waterways were determined.Abnormally high WHO-TEQs were detected in a water （50 pg-TEQ/L） and a sediment sample （41,000 ng-TEQ/kg dry weight） near the industrial solid waste incinerators （ISWIs）.The PCDD/PCDF characteristics agreed well with those of the incinerator-related wastes as seen in the mainstream.These facts indicate that the dioxin pollution in the mainstream could be largely related to the industrial wastes from the ISWIs.Here,a TEQ apportionment method was used to understand the contribution of the pyrogenic sources to the WHO-TEQs.The average contribution ratios of the pyrogenic sources to WHO-TEQs were more than 80% for river waters from the mainstream,indicating that the elevated WHO-TEQs in the mainstream had been largely caused by the ISWIs.

关 键 词：incinerator-related wastes Kanzaki River Basin river water sediment source identification 

分 类 号：X832[环境科学与工程—环境工程]