新型无机-有机化合物(C_(13)H_(16)N_(2))_(2)Mo_(8)O_(26)的合成与晶体结构  

Synthesis and Crystal Structure of a New Type Inorganic Organic Mo_(8)O_(26)(C_(13)H_(16)N_(2))_(2)

作　　者：王婧涵[1] 刘月娥[1] 苏占华[1] 周百斌[1] Wang Jinghan;Liu Yuee;Su Zhanhua;Zhou Baibin(Harbin Normal University)

机构地区：[1]哈尔滨师范大学

出　　处：《哈尔滨师范大学自然科学学报》2012年第4期49-52,共4页Natural Science Journal of Harbin Normal University

基　　金：哈尔滨师范大学青年学术骨干资助项目(09XBKQ11)

摘　　要：采用水热反应合成了一个无机-有机杂化的β-{Mo_(8)O_(26)}簇合物(C_(13)H_(16)N_(2))_(2)Mo_(8)O_(26),并通过FTIR光谱和X-射线单晶衍射对其结构进行了分析.分析结果表明该化合物包含了孤立的β-{Mo_(8)O_(26)}4-簇阴离子和2条二维C_(13)H_(16)N_(2)链,分子之间通过氢键作用连结成三维结构的超分子.An inorganic and organic hybridβ-{Mo_(8)O_(26)}cluster compound Mo_(8)O_(26)(C_(13)H_(16)N_(2))is synthetized by hydrothermal synthesis method and its structure are analyzed by the FTIR spectrun and X-ray monocrystal diffraction.The results of the analysis show that the compound contains isolatedβ-{Mo_(8)O_(26)}4-cluster anion and two C_(13)H_(16)N_(2)chains,the molecules form 3d supramolecular structure through hydrogen bonding.

关 键 词：水热合成 β-{Mo_(8)O_(26)} 晶体结构 

分 类 号：O621.2[理学—有机化学]