重金属Cu^(2+)、Zn^(2+)、Cd^(2+)在海泡石中的吸附特征  

Adsorption characteristic of Cu^(2+),Zn^(2+) and Cd^(2+) by sepiolite

作　　者：杨秀敏[1] 乔艳云[1] 李立欣[1] 赵玉华[1] 

机构地区：[1]黑龙江科技学院资源与环境工程学院,哈尔滨150027

出　　处：《黑龙江科技学院学报》2013年第1期51-54,共4页Journal of Heilongjiang Institute of Science and Technology

基　　金：黑龙江省教育厅科学技术研究项目(12521478)

摘　　要：针对重金属复合污染问题,通过等温吸附实验,研究了海泡石对复合重金属Cu2+、Zn2+、Cd2+的平衡吸附量和吸附选择性,并通过XRD、IR等分析探讨了海泡石的吸附机理。结果表明:海泡石对Cu2+、Zn2+、Cd2+的吸附顺序和富集系数顺序均为Cu2+>Cd2+>Zn2+,并且平衡吸附量随初始溶液质量浓度的提高而增大;海泡石对重金属离子的吸附主要是离子交换吸附及表面络合吸附。该研究证明海泡石具有较强的吸附复合重金属离子的能力,可修复重金属复合污染的废水及土壤。Aimed at addressing the combined contamination of heavy metals, this paper offers the study on the equilibrium adsorption capacity and adsorption selectivity of combined heavy metal Cu^2＋, Zn^2＋ and Cd^2＋ by sepiolite, based on isothermal adsorption test, and the analysis of adsorption mechanism of sepiolite by XRD, IR. The test results show that the adsorption of Cu^2＋, Zn^2＋ and Cd^2＋ by sepiolite and enrichment coefficient are in the order of Cu^2＋, Zn^2＋ and Cd^2＋, and the equilibrium adsorption capacity in- creases with the increase of the initial concentration value. Adsorption of heavy metal ions by sepiolite consists mainly of ion exchange adsorption and surface complexation adsorption. The study proves that sepiolite demonstrates a stronger ability of absorbing combined heavy metal and can find use in remediating the waste water and soil subjected to combined contaminations by heavy metals.

关 键 词：海泡石 重金属离子 吸附 富集系数 吸附机理 

分 类 号：X53[环境科学与工程—环境工程]