可作起爆药的四唑金属含能配合物的合成及性能研究概况  

Energetic Tetrazole-Metal Complexes for Initiating Agent: Synthesis and Propertis Review

作　　者：高晓敏[1] 舒远杰[1] 熊鹰[1] 殷明[1] 李华荣[1] 边亮[1] 

机构地区：[1]中国工程物理研究院化工材料研究所,绵阳621900

出　　处：《高分子通报》2013年第3期99-104,共6页Polymer Bulletin

摘　　要：含能金属配合物在国防领域具有重要意义和良好的应用前景,国内外对四唑类高氮金属含能配合物在用作起爆药方面的研究仍处于初步研究阶段。为了提高起爆药的使用性能和安全性,有必要了解先进高氮金属含能配合物的研究进展,以四唑衍生物为配体的配合物(尤其是5R-四唑阴离子为配体的含能配合物),有望在起爆药方面得到很好的发展,了解它们的合成和性能研究情况,挖掘其在含能材料特别是起爆药领域的应用潜力,有利于进一步探讨其结构与性能。Energetic tetrazole-metal complexes is of great significance and good prospects in national defense area. Some preliminary researches on energetic tetrazole-metal complexes for initiating agent were conducted internationally. The complexes with tetrazole-derivatives, especially with 5R-tetrazole negative ions, as ligands, will be well developed for initiating agent. To probe the future use potentialities as initiating agent and to improve their properties and safety, the recent research situation of the advanced tetrazole-metal complexes is necessary to be reviewed.

关 键 词：绿色起爆药 四唑 含能金属配合物 

分 类 号：O641.4[理学—物理化学]