辛硫磷分子印迹聚合物的合成  

Synthesis of Phoxim Molecularly Imprint Polymer

作　　者：崔新宇[1] 李淼晶[1] 高金霞[1] 曹艳丽[1] 李双晶[1] 

机构地区：[1]牡丹江医学院公共卫生学院

出　　处：《光谱实验室》2013年第2期717-719,共3页Chinese Journal of Spectroscopy Laboratory

基　　金：黑龙江省自然科学基金(QC2012C072)

摘　　要：以辛硫磷为模板分子,丙烯酰胺为功能单体,乙二醇二甲基丙烯酸酯为交联剂,偶氮二异丁腈为引发剂,在甲醇溶液中制备了辛硫磷分子印迹聚合物。该聚合物对模板分子具有良好的选择性,用作液相色谱固定相,很好地分离了模板分子及其结构类似物,结果令人满意。Phoxim molecularly imprint polymer was synthesized in methanol solution with phoxim as template molecular, acrylamide as functional monomer, ethylene dimethacrylate as crosslinker,azobisisobutyronitrile as initiator. The results showed that polymer had good selectivity on template molecular, and can be used as stationary phase of high performance liquid chromatogram, then template molecular and its structural analogues were well separated with satisfied results.

关 键 词：分子印迹 辛硫磷 高效液相色谱 

分 类 号：O657.72[理学—分析化学]