叠氮化反应进展(Ⅰ)——羰基化合物叠氮化  

Advances in the azidation reaction(Ⅰ)—azidation of carbonyl compounds

作　　者：江玉波[1] 韩春美[2] 梁雪秋[1] 杨保民[1] 

机构地区：[1]昆明理工大学理学院,云南昆明650500 [2]昆明理工大学机电学院,云南昆明650500

出　　处：《化学研究与应用》2013年第3期273-279,共7页Chemical Research and Application

基　　金：国家自然科学基金项目(21262020)资助;云南省科技厅科技计划项目(KKSY201207047)资助

摘　　要：有机叠氮化合物含有叠氮基高能活性官能团,是一类重要的有机合成中间体及目标,目前已被广泛应用,该类化合物均来自叠氮化反应。本文主要综述了该类反应近些年的研究进展,阐述了羰基化合物的叠氮化反应的进展情况,主要包括醛、羧酸及羧酸衍生物的反应情况,并对部分反应机理进行了讨论。Organic azides were a kind of important targets and intermediates in organic synthesis. Beating energy-rich azido group, these compounds were widely used in many fields. These organonitrogen compounds were mostly prepared by the reaction of azidization. This paper mainly reviewed the recent advances in the azidization reaction of carbonyl compounds including aldehydes ,caxboxylic acid and its derivatives. Mechanisms of some reactions were also discussed.

关 键 词：有机叠氮 合成 叠氮化反应 羰基化合物 

分 类 号：O621.3[理学—有机化学]