“SERGEANTS AND SOLDIERS RULE” IN HELICAL SUBSTITUTED- ACETYLENE COPOLYMER EMULSIONS  

作　　者：Xuan Liu Ci Song Xiao-feng Luo Wan-tai Yang 邓建平 

机构地区：[1]State Key Laboratory of Chemical Resource Engineering,College of Materials Science and Engineering,Beijing University of Chemical Technology

出　　处：《Chinese Journal of Polymer Science》2013年第1期179-186,共8页高分子科学（英文版）

基　　金：supported by the National Natural Science Foundation of China (Nos. 21174010, 20974007);the Fundamental Research Funds for the Central Universities (ZZ1117)

摘　　要：The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the （co）polymer chains in the nanoparticles adopt helical structures of a predominant helicity, and the copolymers follow the ＂sergeants and soldiers rule＂ in forming helical structure.The ＂sergeants and soldiers rule＂ occurring in helical copolymer emulsions derived from an achiral monomer （M1） and a chiral monomer （M2） was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the （co）polymer chains in the nanoparticles adopt helical structures of a predominant helicity, and the copolymers follow the ＂sergeants and soldiers rule＂ in forming helical structure.

关 键 词：Sergeants and soldiers rule Helical polymer Emulsion. 

分 类 号：O631.3[理学—高分子化学]