Er^(3+),Yb^(3+):YGG激光陶瓷粉体制备与性能研究  

Study on Properties and Preparation of Er^(3+),Yb^(3+):YGG Laser Ceramics Precursor

作　　者：董彦珉[1] 孙晶[1] 曾繁明[1] 李伟行[1] 腾飞[1] 

机构地区：[1]长春理工大学化学与环境工程学院,长春130022

出　　处：《硅酸盐通报》2013年第3期401-404,共4页Bulletin of the Chinese Ceramic Society

摘　　要：本文以Y2O3,Ga2O3,Er2O3,Yb2O3,柠檬酸为原料,利用溶胶-凝胶法制备出Er3+,Yb3+∶YGG激光陶瓷前驱粉体。对粉体进行XRD测试,结果表明在本实验条件下,粉体的最佳煅烧温度为800℃。红外光谱表明800℃时NO3-,OH-等离子已被分解。扫描电镜观察发现,粉体颗粒为似球形,粒径约为35 nm,结合XRD数据计算,发现一个颗粒由2～3个晶粒组成,可见溶胶-凝胶法制备的粉体团聚程度相对较低。对粉体进行荧光光谱测试,结果表明由于Er3+的4I13/2-4I15/2的能级跃迁引起的荧光发射,其最强峰位于1530 nm处。Er3＋ , Yb3 ＋ ： YGG laser ceramics precursor was synthesized by sol-gel method with Y2O3, Ga2 O3, Er2 O3, Yb2 O3 and the citric acid. XRD analysis showed that the optimum calcination temperature of precursor was 800 ℃. IR test showed that NO3-, OH- have been calcined, it can be concluded the composition of the powders of YGG. SEM test showed that the diameter of the power is 35 nm. With the result of the XRD, one particle was composed by 2-3 crystal particles, The strongest fluorescence peak of Er3＋ , yb3＋： YGG laser ceramics precursor was 1530 nm, that was ^4Ⅰ_13/2-^4Ⅰ_15/2.

关 键 词：溶胶-凝胶法 Er3+ Yb3+∶YGG 激光陶瓷 荧光 

分 类 号：TQ174[化学工程—陶瓷工业]