固相法制备钇掺杂的钛酸钡锶钙陶瓷的介电和热释电性能(英文)  

Dielectric and Pyroelectric Properties of Y-doped Ba_(0.6)Sr_(0.3)Ca_(0.1)TiO_3 Ceramics by Solid-state Reaction Technique

作　　者：曹盛[1] 毛朝梁[1] 姚春华[1] 曹菲[1] 王根水[1] 董显林[1] 

机构地区：[1]中国科学院上海硅酸盐研究所,中国科学院无机功能材料与器件重点实验室,上海200050

出　　处：《无机材料学报》2013年第4期447-452,共6页Journal of Inorganic Materials

基　　金：Funds of National Natural Science Foundation of China(U0937603);National Natural Sceince Foundation of China(51002173)

摘　　要：采用固相反应法制备了Y掺杂(Ba0.6Sr0.3Ca0.1)1-xYxTi0.999Mn0.001O3(0≤x≤0.007)陶瓷,重点研究了Y含量对BSCT基陶瓷的显微结构、介电性能和热释电性能的影响。结果表明:随着Y含量的增加,BSCYxTM陶瓷的平均晶粒尺寸逐渐减小,介电常数、介电损耗、居里温度和热释电系数均呈现先增加后减小的趋势。当Y掺杂量为0.7mol%时,BSCYxTM陶瓷的平均晶粒尺寸最小为3.1μm,且探测优值Fd较大,最大值可达8.22×10-5Pa-1/2(700 V/mm,30℃),高于采用溶胶-凝胶法制备的同组分陶瓷的探测优值5.91×10-5Pa-1/2。（Ba0.6Sr0.3Ca0.1）1-xYx Ti0.999Mn0.001O3（0≤x≤0.007） ceramics were prepared by the solid-state reaction technique.The effects of Y doping on the microstructure,dielectric properties and pyroelectric properties were investigated.The average grain size decreases with the increase of Y concentration.The dielectric and pyroelectric properties measurement results show that the dielectric constant,dielectric loss,T c and pyroelectric coefficient all initially increase and then decrease with Y concentration.And the pyroelectric figure of merit F d can be improved by the Y doping.The specimen doped with 0.7mol%Y shows a higher maximum F d value of 8.22×10-5 Pa-1/2 under 700 V/mm near 30℃ with the smallest average grain size of 3.1 μm,indicating its promising application in infrared thermal imaging arrays devices.

关 键 词：(Ba Sr Ca)TiO3 陶瓷 介电性能 热释电性能 

分 类 号：TQ174[化学工程—陶瓷工业]