One-pot synthesis of selenocarbamates from isocyanates and diselenides using the Zn/AlCl_3 system  

One-pot synthesis of selenocarbamates from isocyanates and diselenides using the Zn/AlCl_3 system

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作  者:Barahman Movassagh Mona Moradi 

机构地区:[1]Department of Chemistry,K.N.Toosi University of Technology

出  处:《Chinese Chemical Letters》2013年第3期192-194,共3页中国化学快报(英文版)

基  金:the K.N.Toosi University of Technology Research Council for financial assistance

摘  要:Several N-alkyl/aryl-Se-alkyl/(aryl)selenocarbamates were prepared from various isocyanates and diselenides by reductive cleavage of Se-Se bond with the Zn/AIC]3 system in dry acetonitrile at 80 ℃.Several N-alkyl/aryl-Se-alkyl/(aryl)selenocarbamates were prepared from various isocyanates and diselenides by reductive cleavage of Se-Se bond with the Zn/AIC]3 system in dry acetonitrile at 80 ℃.

关 键 词:SelenocarbamatesDiselenideslsocyanatesZinc selenolateZn/AICI3 system 

分 类 号:O623.763[理学—有机化学]

 

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