Molecular Characterization of Hydrotreated Atmospheric Residue Derived from Arabian Heavy Crude by GC FI/FD TOF MS and APPI FT-ICR MS  

作　　者：Diao Rui Wang Wei Wang Naixin Liu Zelong Dai Lishun Tian Songbai 

机构地区：[1]Research Institute of Petroleum Processing,SINOPEC

出　　处：《China Petroleum Processing & Petrochemical Technology》2012年第4期80-88,共9页中国炼油与石油化工（英文版）

基　　金：supported by the National Basic Research Program of China (2010CB226901)

摘　　要：High resolution mass spectrometry in combination with distillation and SARA fractionation provides us an opportunity for in-depth understanding about the hydrotreating process at the molecular level. In this study, the atmospheric residue derived from Arabian heavy crude and its hydrotreated products were initially subjected to distillation and SARA fractionation. The saturates were characterized by GC FI/FD TOF MS. The aromatics and resins were characterized by APPI FT-ICR MS. Compositional changes of different compounds (paraffins, naphthenes, aromatic hydrocarbons, and heteroatomic compounds) contained in different distillates (vacuum gas oil, vacuum residue) were obtained. More detailed knowledge about the hydrotreating process was achieved.High resolution mass spectrometry in combination with distillation and SARA fractionation provides us an op- portunity for in-depth understanding about the hydrotreating process at the molecular level. In this study, the atmospheric residue derived from Arabian heavy crude and its hydrotreated products were initially subjected to distillation and SARA fractionation. The saturates were characterized by GC FI/FD TOF MS. The aromatics and resins were characterized by APPI FT-ICR MS. Compositional changes of different compounds （paraffins, naphthenes, aromatic hydrocarbons, and heteroatomic compounds） contained in different distillates （vacuum gas oil, vacuum residue） were obtained. More detailed knowledge about the hydrotreating process was achieved.

关 键 词：hydrotreating petroleum residue FT-ICR MS GC FI/FD TOF MS 

分 类 号：TE624[石油与天然气工程—油气加工工程]