氘代有机物的表征技术  

Characterization techniques of deuterated organic compounds

作　　者：胡睿[1] 熊晓玲[1] 阚文涛[1] 

机构地区：[1]中国工程物理研究院核物理与化学研究所,四川绵阳621900

出　　处：《化学试剂》2013年第4期329-332,共4页Chemical Reagents

基　　金：国家青年科学基金资助项目(51103140)

摘　　要：氘代有机物的种类越来越多,氘代基团、氘代率以及含氘量都是分子中需要表征的重要信息。综述了红外光谱、拉曼光谱、质谱、氢核磁共振波谱、分光光度法等在表征以上参数的定性定量方法,并初步总结了氢原子被氘代后体现在红外光谱、质谱上的变化规律。There are more and more types of deuterated organic compound.It is necessary to characterize some information about ideuterated groups,deuterated rate and the amount of containing deuterium atoms.In order to obtain above parameters,some qualitative and quantitative methods were summarized about infrared spectroscopy,Raman spectroscopy,mass spectrometry,hydrogen nuclear magnetic resonance spectroscopy and spectrophotometry.Aslo,IR and mass spectrometry was preliminary summarized after hydeogen atom was replaced by deuterium atom.

关 键 词：表征 氘代有机化合物 

分 类 号：O657.3[理学—分析化学]