无溶剂合成甲基二羟乙基烯丙基氯化铵  

Solvent free synthesis of methyl dihydroxyethyl allyl ammonium chloride

作　　者：毛桃嫣[1] 郑成[2] 林璟[2] 陈晓玲[2] 黄晓罗[2] 邢旭[2] 张利萍[3] 

机构地区：[1]广西大学化学化工学院,广西南宁530004 [2]广州大学精细化工研究所,广东广州510006 [3]广州天赐有机硅科技有限公司,广东广州510660

出　　处：《化工学报》2013年第5期1884-1889,共6页CIESC Journal

基　　金：广东省部产学研项目(20120980);广州市教育局科技项目穗教科[2013]26号;国家级大学生创新训练项目(201211078006)~~

摘　　要：近十年来,特别是近几年来,有机化学工作者将无溶剂条件下的有机化学反应提出来进行专门的研究。大量研究结果证明[1-4],许多有机化学反应可以在无溶剂下进行,取得了令人欣喜的结果。与有溶剂条件下的有机反应相比,Methyl dihydroxyethyl allyl ammonium chloride（MDAAC）was synthesized from N-methyl diethanolamine（MDEA）and allyl chloride by the solvent-free synthesis method.The effects of reaction time,reaction temperature and reactant molar ratio on reaction conversion rate were studied.The optimum process of synthesizing MDAAC obtained by orthogonal experiment was 60 min reaction time,50℃ reaction temperature and 1∶1.3 molar ratio of MDEA and allyl chloride.The target product was purified by recrystallization and the yield of product was 97%.The structure of product was characterized by IR,1H NMR and 13C NMR.

关 键 词：无溶剂合成 甲基二羟乙基烯丙基氯化铵 N-甲基二乙醇胺 

分 类 号：TQ423.12[化学工程]