新型磷杂菲酯类衍生物的合成及热稳定性研究  

Synthesis and Thermal Stability of Novel Phosphaphenanthrene Ester Derivatives

作　　者：郑金云[1] 甄晓敏[1] 李肖[1] 赵玉芬[1,2] 

机构地区：[1]郑州大学化学与分子工程学院,河南省化学生物与有机化学重点实验室,河南郑州450001 [2]厦门大学化学化工学院,福建省化学生物重点实验室,福建厦门361005

出　　处：《郑州大学学报（工学版）》2013年第2期15-20,共6页Journal of Zhengzhou University（Engineering Science）

基　　金：国家自然科学基金资助项目(20732004);河南省博士后基金资助项目

摘　　要：磷杂菲衍生物是一类重要的阻燃材料.由磷杂菲与甲醛反应得到的中间体分别与各种酰氯反应得到一系列新型的磷杂菲酯类衍生物,利用1H NMR、13C NMR、31P NMR、FT-IR、HR-MS和ESI-MS对化合物的结构做了表征.讨论了催化剂用量、物料比、溶剂、反应物浓度、反应时间及温度对反应的影响,并对反应进行优化.对代表化合物的热稳定性做了测试,结果表明这类磷杂菲酯类衍生物具有良好的热稳定性,可以作为阻燃材料使用.Phosphaphenanthrene＇ s derivatives are an important flame retardant materials. A series of new es- ter derivatives of phosphaphenanthrene were prepared by the various acyl chlorides and the intermediate which was prepared by phosphaphenanthrene and formaldehyde, and their structures were characterized by 1H NMR,13C NMR,31P NMR,FT - IR,HR - MS and ESI - MS. The influences of catalyst, material ratio, sol- vent, reactants concentration, reaction time and temperature on the reaction were discussed in detail, while the reaction process was optimized. The thermal stabilities of the compounds were recorded, and the results show that they have excellent thermal stability. The compounds are potential flame retardant materials.

关 键 词：磷杂菲酯类衍生物 合成 热稳定性 阻燃 

分 类 号：O627.51[理学—有机化学]