附着生物膜的泥沙颗粒对磷的吸附特性研究  

Study on phosphorus adsorption to the sand attached with surface coatings

作　　者：申禹[1] 李玲[1] 

机构地区：[1]清华大学水沙科学与水利水电工程国家重点实验室,北京100084

出　　处：《水利学报》2013年第4期495-499,共5页Journal of Hydraulic Engineering

基　　金：国家自然科学基金项目(51079071;51039002)

摘　　要：附着在泥沙表面的生物膜具有很强的吸附特性,对水环境中营养盐等物质的迁移转化具有重要的作用。本文对去除生物膜的泥沙和表面附着生物膜的泥沙分别进行了吸附营养盐磷的实验研究,对比了去除生物膜与附着生物膜的泥沙颗粒对磷的吸附能力,研究了附着生物膜的泥沙颗粒吸附磷的动力学及热力学特征。研究结果表明,去除生物膜的泥沙对磷的吸附性微小,而附着生物膜的泥沙颗粒对磷的吸附能力很强,在相同条件下附着生物膜的泥沙颗粒的吸附量比纯净泥沙吸附量高出1个数量级;同时附着生物膜的泥沙颗粒吸附磷的动力学特性符合准二级动力学模型,等温吸附特性符合Langmuir等温式,吸附速率和平衡吸附量随泥沙粒径减小而增大。Surface coatings attached to the sand have a strong adsorption and play an important role in the migration and transformation of nutrients and other substances in water environment. Adsorption experiments were carried out by using sand removed surface coatings and sand with surface coatings attached, respec tively. The adsorption ability of phosphorus to two different kinds of sand was compared. The kinetic and thermodynamic adsorption of phosphorus to the sand with surface coatings attached was studied. The results show that the sand removed surface coatings has little adsorption to phosphorus. The sand with surface coat ings cultured has a strong adsorption to phosphorus, with equilibrium adsorption capacity one order of mag nitude higher than that of sand removed surface coatings. Phosphorus adsorption by the sand with surface coatings cultured was consistent with pseudosecond order kinetic model. Isotherms fitted the Langmuir mod els well. Adsorption rate and equilibrium adsorption capacity increases as the sand particle size decreasing.

关 键 词：生物膜 泥沙 吸附 磷 

分 类 号：TV141.2[水利工程—水力学及河流动力学]