含能配合物研究新进展  

Recent Research Progresses in Energetic Coordination Compounds

作　　者：张同来[1] 武碧栋[1] 杨利[1] 周遵宁[1] 张建国[1] 

机构地区：[1]北京理工大学爆炸科学与技术国家重点实验室,北京100081

出　　处：《含能材料》2013年第2期137-151,共15页Chinese Journal of Energetic Materials

基　　金：爆炸科学与技术国家重点实验室(No.QNKT12-02和YBKT10-05);应用物理化学重点实验室(No.9140C3703051105和9140C370303120C37142)

摘　　要：含能配合物具有结构稳定、安定性能好、高能钝感等特点,在起爆药、点火药、含能催化剂领域具有重要的用途。本研究概述了近年来在高氯酸类、叠氮类、硝酸类、硝基酚类等五大类含能配合物的分子结构、耐热性能及感度性能等方面的最新研究结果,详细阐述了金属离子对含能配合物性能的影响规律,并展望了含能配合物的发展方向。Energetic coordination compounds are potential explosive materials with structural stability, high-energy ana lOW sensitivity. All of these compounds have potential applications in ammunition and civil explosives as primary explosive, ignition composition and energetic catalyst. Many achievements of studying on the crystal structures, thermal decomposition properties and explosive properties of the energetic compounds based on perchlorate compounds, azide compounds, nitrate compounds, polynitrophenol compounds and other compounds were briefly summarized and evaluated. The effects of metal ions on properties of energetic coordination compounds were described in detail. Some prospects of the energetic compounds were proposed based on the results involved.

关 键 词：综述 高氯酸类配合物 叠氮类配合物 硝酸类配合物 硝基酚类配合物 分子结构 

分 类 号：O641.4[理学—物理化学]