烯丙基甲酚醚/双马来酰亚胺/二烯丙基双酚A共混体的热稳定性研究  

Thermal Stability Study for Allyl Methyl Phenol Ether/Bismaleimide/Diallyl Bisphenol A Ternary Blend

作　　者：喻淼[1,2] 樊振[2] 柳准[3] 刘景民[3] 付宁宁[1] 张宁[1] 张果[1] 

机构地区：[1]黄淮学院化学化工系,驻马店463000 [2]河南天方药业股份有限公司,驻马店463000 [3]湖北省化学研究院,武汉430074

出　　处：《高分子通报》2013年第5期71-75,共5页Polymer Bulletin

摘　　要：双马来酰亚胺(BMI)/二烯丙基双酚-A(DABP-A)共混体树脂体系,具有高韧性和优异的耐热性能,但粘度大,导致加工工艺复杂,应用困难。而烯丙基甲酚醚(AMPE)含有活性基团,与上述树脂体系能发生交联反应,将其作为活性稀释剂,选择合适比例,能在减小粘度的同时,提高体系的机械强度和耐热性能。实验中将AMPE加入到BMI/DABPA树脂体系,并改变AMPE在树脂体系中的质量分数,测定质量分数与体系粘度、热稳定性等性能之间的关系,确定最佳的比例为AMPE∶BMI∶DABPA=10～20∶36∶29.2,而热失重实验也表明,复合材料热稳定性得到了进一步提高。该结论对于企业改进生产工艺,降低生产成本,提高产品质量,改善生产效益,具有重要意义。The bismaleimide （BMI）/diallyl bisphenol A （DABPA） blend system is an important system for usage for its high stability, but its high viscosity prevent its usage in factory. Possessing high active group, allyl methyl phenol ether can react with BMI/DABPA resin through cross-linking reaction under heat condition, it has been used as the reactive diluent. Thus AMPE can reduce the viscosity of the resin system and increase heat resistance. Through determination the viscosity and TGA data of this blend containing different content allyl cresol ether, an appropriate proportion （AMPE： BMI： DABPA = 10-20： 36：29.2） has been obtained to increase the production benefit. This conclusion will be helpful for industry to increase product quality and productivity effect.

关 键 词：双马来酰亚胺树脂 二烯丙烯双酚A 烯丙基甲酚醚 活性稀释剂 

分 类 号：TQ323.7[化学工程—合成树脂塑料工业]