Meso-四(4-羧基苯基)卟啉及其金属配合物的合成及光谱性质研究  

Synthesis and Spectral Properties of Meso-tetra (4-carboxyphenyl)Porphyrin and Its Metal Complexes

作　　者：秦琳琳[1] 阎雁[1] 

机构地区：[1]广东工业大学轻工化工学院,广东广州510006

出　　处：《广东化工》2013年第9期21-22,11,共3页Guangdong Chemical Industry

摘　　要：文章用Adler法将吡咯和羧基苯甲醛反应合成了5,10,15,20-四(4-羧基苯基)卟啉(TCPP),用反复调pH法得到了较纯净的TCPP,解决了TCPP分离纯化困难的问题;并合成了其Zn(II)和Co(II)的配合物,并利用紫外,1H-NMR荧光,红外和EPR对其光谱进行了研究。In the paper,meso-tetra（4-carboxyphenyl） porphyrin（TCPP） was synthesized according to the Adler method with pyrrole and carboxybenzaldehyde.In order to solve the separation and purification difficult problem of TCPP,slao repeated a new way to obtain a relatively pure TCPP by adjusting pH.And their related zinc（II） and 1cobalt（II） complexes are also synthesized,These compounds have been characterized by UV-Vis,1H-NMR,FL,IR and EPR spectral determinations.

关 键 词：四羧基苯基卟啉 金属配合物 EPR 

分 类 号：TQ171.112[化学工程—玻璃工业]