微波辐射法制备富马酸-丙烯酸共聚物及其助洗性能的研究  

Synthesis of fumaric-acrylic acid copolymer by microwave radiation and its detergent properties

作　　者：崔桂玲[1] 鲁莉华[1] 董磊[1] 付敏[1] 蒋爱雯[1] 

机构地区：[1]青岛农业大学化学与药学院,山东青岛266109

出　　处：《青岛农业大学学报（自然科学版）》2012年第4期299-301,共3页Journal of Qingdao Agricultural University(Natural Science)

基　　金：2012年地方高校国家级大学生创新创业训练计划项目(201210435023)

摘　　要：用微波辐射合成工艺代替了传统的溶液聚合法,制备了富马酸-丙烯酸共聚物(FAcoAA),研究了其助洗性能,并与微波辐射法所制备的马来酸酐-丙烯酸共聚物(FAcoAA)产品的助洗性能进行了比较。实验得出微波辐射合成FAcoAA的较佳条件为:富马酸(FA)与丙烯酸(AA)的质量比为m(FA):m(AA)=1:10,引发剂过硫酸钠的用量为单体总质量的6%,微波功率为600W,辐射时间为8min。The fumaric- acrylic acid copolymer {FAcoAA} was synthesized by the microwave radiation instead of the traditional method of solution polymerization. The detergent properties were also studied, as well as compared with the maleic anhydride - acrylic copolymer （ MAcoAA } synthesized via microwave - assisted method. The experiments showed that the optimum conditions were as follows ： mass ratio of FA to AA is 1 ： 10 ; the amount of sodium persulfate is 6% of the total monomers＇mass; the microwave power is 600W and the radiation time is 8min.

关 键 词：富马酸 丙烯酸共聚物 助洗性能 微波辐射 

分 类 号：O632[理学—高分子化学]