A new family of supramolecular multiferrocenyl rhomboids:Synthesis,characterization,and their electrochemical behavior  

作　　者：Jiang-Kun Ou-Yang Li-Jun Chen Lin Xu Cui-Hong Wang Hai-Bo Yang 

机构地区：[1]Shanghai Key Laboratory of Green Chemistry and Chemical Processes,Department of Chemistry,East China Normal University

出　　处：《Chinese Chemical Letters》2013年第6期471-474,共4页中国化学快报（英文版）

基　　金：financially supported by NSFC(Nos.21132005 and 91027005)

摘　　要：Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ^（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated.Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ^（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated.

关 键 词：Supromolecular metallacycle Coordination-driven self-assembly Multiferrocenyl rhomboid Electrochemical behavior 

分 类 号：O627.81[理学—有机化学]