异丙醇铝溶胶-凝胶掺杂的SiO_2-Al_2O_3/PEG导热增强型定形相变储能材料  

Thermal conductivity enhanced SiO_2-Al_2O_3/PEG form-stable phase change material based on the sol-gel doping of aluminum isopropanol

作　　者：邱美鸽[1] 唐炳涛[1] 张淑芬[1] 贾超[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,大连116024

出　　处：《复合材料学报》2013年第3期93-99,共7页Acta Materiae Compositae Sinica

基　　金：国家自然科学基金(20804007);教育部高等学校博士学科点专项科研基金(200801411032);教育部长江学者和创新团队发展计划(IRT0711)

摘　　要：以异丙醇铝(AIP)与正硅酸乙酯(TEOS)为溶胶前驱体、聚乙二醇(PEG)为相变组分,经超声辅助溶胶-凝胶过程制备了SiO2-Al2O3/PEG导热增强型定形相变储能材料。利用FTIR和XRD对SiO2-Al2O3/PEG进行结构表征及结晶性能测定,利用DSC与TGA研究其热性能与热稳定性,利用显微热台与数码拍照技术测试材料的定形效果;利用热导率仪测定了材料的导热系数。结果表明,SiO2-Al2O3/PEG的相变焓值可以达到100J/g以上,低于300℃时具有良好的热稳定性,当SiO2-Al2O3/PEG中的铝硅质量比为0.2∶1时,其导热系数可达0.414W/(m.K),导热性能比纯PEG提高39.3%,并具有良好的定形效果。The thermal conductivity enhanced SiO2 - A12Oa/PEG form- stable phase change composite was synthesized through the ultrasound assisted sol-gel method with aluminum isopropanol （AIP） and tetraethoxysilane as the sol precursor, and polyethylene glycol （PEG） as the phase change component. FTIR and XRD were used to characterize the structure and measure the crystallization properties of the SiOz - A12Oa/PEG. The thermal performance and thermal stability were analyzed by DSC and TGA. The formstable performance was fixed by microscopic heating stage and digital photo technology. The thermal conductivity of the SiOz - A12 Oa/PEG were measured by the thermal conductivity meter. The results show that the phase change enthalpy of the product reaches above 100 J/g, and the material has a good thermal stability within 300 ℃. When the mass ratio of A1 to Si is 0.2 = 1, the thermal conductivity of the composite reaches 0. 414 W/（m . K）, which increases by 39.3G. Besides, it has an excellent form stable performance.

关 键 词：导热增强 溶胶-凝胶 聚乙二醇 异丙醇铝 相变储能 

分 类 号：TB332[一般工业技术—材料科学与工程]