Bismuth Modified Porous Silica Preparation,Characterization and Photocatalytic Activity Evaluation for Degradation of Isoproturon  

作　　者：Anil Kumar Reddy Police Srinivas Basavaraju Durga Kumari Valluri Subrahmanyam Machiraju 

机构地区：[1]Inorganic and Physical Chemistry Division,Indian Institute of Chemical Technology,Hyderabad 500607,India

出　　处：《Journal of Materials Science & Technology》2013年第7期639-646,共8页材料科学技术（英文版）

基　　金：PAKR and MS thank CSIR,New Delhi for funding this work under Emeritus Scientist Scheme

摘　　要：Porous silica prepared by using an acrylic emulsion has been impregnated with bismuth ion resulting in Bi2Si05 species containing surface. The as-prepared materials have been characterized by X-ray diffraction spectroscopy （XRD）, X-ray photoelectron spectroscopy （XPS）, UV-Vis diffuse reflectance spectroscopy （UV-Vis DRS）, scanning electron microscopy （SEM）, energy dispersive analysis of X-ray （EDAX）, transmission electron microscopy （TEM）, Fourier transform infrared spectroscopy （FTIR） and N2 adsorption/desorption techniques. EDAX analysis confirms the penetration of bismuth ions into the framework of silica to form Bi2SiO5, which is substantiated by XRD. The UV-Vis DRS shows that the catalysts are optically active and XPS confirms the inclusion of bismuth into the framework of silica. FTIR spectra illustrate the formation of Bi-O-Si linkages in the porous silica framework. SEM and TEM show the spherical morphology, whereas N2 adsorption/desorption study confirms the porosity of the prepared materials. The photocatalytic activity of the material is evaluated for the degradation of isoproturon herbicide and it is found that the material is active as compared to the commercial P-25 Degussa TiO2.Porous silica prepared by using an acrylic emulsion has been impregnated with bismuth ion resulting in Bi2Si05 species containing surface. The as-prepared materials have been characterized by X-ray diffraction spectroscopy （XRD）, X-ray photoelectron spectroscopy （XPS）, UV-Vis diffuse reflectance spectroscopy （UV-Vis DRS）, scanning electron microscopy （SEM）, energy dispersive analysis of X-ray （EDAX）, transmission electron microscopy （TEM）, Fourier transform infrared spectroscopy （FTIR） and N2 adsorption/desorption techniques. EDAX analysis confirms the penetration of bismuth ions into the framework of silica to form Bi2SiO5, which is substantiated by XRD. The UV-Vis DRS shows that the catalysts are optically active and XPS confirms the inclusion of bismuth into the framework of silica. FTIR spectra illustrate the formation of Bi-O-Si linkages in the porous silica framework. SEM and TEM show the spherical morphology, whereas N2 adsorption/desorption study confirms the porosity of the prepared materials. The photocatalytic activity of the material is evaluated for the degradation of isoproturon herbicide and it is found that the material is active as compared to the commercial P-25 Degussa TiO2.

关 键 词：Acrylic emulsion Emulsion polymerization technique Porous silica Bi2SiO5 Photocatalyfic degradation lsoproturon 

分 类 号：O643.36[理学—物理化学] TQ457[理学—化学]